Pushing the photodelivery of nitric oxide to the visible: Are {FeNO}7 complexes good candidates?

Photodelivery of NO requires stable compounds which can be made reactive by irradiation with (visible) light. Traditional {MNO}6 complexes require a substantial ligand design to shift their absorption spectra to the appropriate region of the electromagnetic spectrum. [Fe((CH2Py2)2Me[9]aneN3)(NO)](BF...

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Detalles Bibliográficos
Publicado: 2017
Materias:
Absorption spectroscopy
Light sources
Air stable
Electromagnetic spectra
Ligand design
Octahedral coordination
Photo-detachment
Nitric oxide
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v46_n46_p16058_Levin
http://hdl.handle.net/20.500.12110/paper_14779226_v46_n46_p16058_Levin
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_14779226_v46_n46_p16058_Levin
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spelling paper:paper_14779226_v46_n46_p16058_Levin2023-06-08T16:18:17Z Pushing the photodelivery of nitric oxide to the visible: Are {FeNO}7 complexes good candidates? Absorption spectroscopy Light sources Air stable Electromagnetic spectra Ligand design Octahedral coordination Photo-detachment Nitric oxide Photodelivery of NO requires stable compounds which can be made reactive by irradiation with (visible) light. Traditional {MNO}6 complexes require a substantial ligand design to shift their absorption spectra to the appropriate region of the electromagnetic spectrum. [Fe((CH2Py2)2Me[9]aneN3)(NO)](BF4)2 is a new {FeNO}7 octahedral coordination compound, which is thermally and air-stable in solution. Illumination with a 450 nm light source induces significant photodetachment of the coordinated NO (NO = 0.52 mol einstein-1), suggesting that {FeNO}7 compounds can be in fact suitable compounds for therapeutic NO-photorelease. © The Royal Society of Chemistry 2017. 2017 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v46_n46_p16058_Levin http://hdl.handle.net/20.500.12110/paper_14779226_v46_n46_p16058_Levin
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Absorption spectroscopy
Light sources
Air stable
Electromagnetic spectra
Ligand design
Octahedral coordination
Photo-detachment
Nitric oxide
spellingShingle Absorption spectroscopy
Light sources
Air stable
Electromagnetic spectra
Ligand design
Octahedral coordination
Photo-detachment
Nitric oxide
Pushing the photodelivery of nitric oxide to the visible: Are {FeNO}7 complexes good candidates?
topic_facet Absorption spectroscopy
Light sources
Air stable
Electromagnetic spectra
Ligand design
Octahedral coordination
Photo-detachment
Nitric oxide
description Photodelivery of NO requires stable compounds which can be made reactive by irradiation with (visible) light. Traditional {MNO}6 complexes require a substantial ligand design to shift their absorption spectra to the appropriate region of the electromagnetic spectrum. [Fe((CH2Py2)2Me[9]aneN3)(NO)](BF4)2 is a new {FeNO}7 octahedral coordination compound, which is thermally and air-stable in solution. Illumination with a 450 nm light source induces significant photodetachment of the coordinated NO (NO = 0.52 mol einstein-1), suggesting that {FeNO}7 compounds can be in fact suitable compounds for therapeutic NO-photorelease. © The Royal Society of Chemistry 2017.
title Pushing the photodelivery of nitric oxide to the visible: Are {FeNO}7 complexes good candidates?
title_short Pushing the photodelivery of nitric oxide to the visible: Are {FeNO}7 complexes good candidates?
title_full Pushing the photodelivery of nitric oxide to the visible: Are {FeNO}7 complexes good candidates?
title_fullStr Pushing the photodelivery of nitric oxide to the visible: Are {FeNO}7 complexes good candidates?
title_full_unstemmed Pushing the photodelivery of nitric oxide to the visible: Are {FeNO}7 complexes good candidates?
title_sort pushing the photodelivery of nitric oxide to the visible: are {feno}7 complexes good candidates?
publishDate 2017
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v46_n46_p16058_Levin
http://hdl.handle.net/20.500.12110/paper_14779226_v46_n46_p16058_Levin
_version_ 1768542612819542016

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