{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour

The newly obtained complexes [NiII8LnIII6(Piv)16(teaH)6(OCH3)2(CO3)2(H2O)2] Ln = Gd, Dy, show a remarkable μ5-carbonate bridged octanuclear planar {Ni4Ln4} core further capped with embedded {Ni3Ln} cubane motifs to afford a rod shaped nano-sized molecule of about 1.2 × 2.8 nm. Unusual MCE behaviour...

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Detalles Bibliográficos
Autor principal:	Albores, Pablo
Publicado:	2016
Materias:	Ferromagnetic materials Ferromagnetism Coordination clusters Ferromagnetic and anti-ferromagnetic Heteronuclear Low-lying excited state Nano sized Rod-shaped Nickel
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v45_n20_p8566_Guarda http://hdl.handle.net/20.500.12110/paper_14779226_v45_n20_p8566_Guarda
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_14779226_v45_n20_p8566_Guarda
record_format	dspace
spelling	paper:paper_14779226_v45_n20_p8566_Guarda2023-06-08T16:18:15Z {Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour Albores, Pablo Ferromagnetic materials Ferromagnetism Coordination clusters Ferromagnetic and anti-ferromagnetic Heteronuclear Low-lying excited state Nano sized Rod-shaped Nickel The newly obtained complexes [NiII8LnIII6(Piv)16(teaH)6(OCH3)2(CO3)2(H2O)2] Ln = Gd, Dy, show a remarkable μ5-carbonate bridged octanuclear planar {Ni4Ln4} core further capped with embedded {Ni3Ln} cubane motifs to afford a rod shaped nano-sized molecule of about 1.2 × 2.8 nm. Unusual MCE behaviour has been found due to multiple low lying excited states arising from competing ferromagnetic and anti-ferromagnetic Ni-Ni and Ni-Ln exchange interactions. © 2016 The Royal Society of Chemistry. Fil:Alborés, P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2016 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v45_n20_p8566_Guarda http://hdl.handle.net/20.500.12110/paper_14779226_v45_n20_p8566_Guarda
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Ferromagnetic materials Ferromagnetism Coordination clusters Ferromagnetic and anti-ferromagnetic Heteronuclear Low-lying excited state Nano sized Rod-shaped Nickel
spellingShingle	Ferromagnetic materials Ferromagnetism Coordination clusters Ferromagnetic and anti-ferromagnetic Heteronuclear Low-lying excited state Nano sized Rod-shaped Nickel Albores, Pablo {Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour
topic_facet	Ferromagnetic materials Ferromagnetism Coordination clusters Ferromagnetic and anti-ferromagnetic Heteronuclear Low-lying excited state Nano sized Rod-shaped Nickel
description	The newly obtained complexes [NiII8LnIII6(Piv)16(teaH)6(OCH3)2(CO3)2(H2O)2] Ln = Gd, Dy, show a remarkable μ5-carbonate bridged octanuclear planar {Ni4Ln4} core further capped with embedded {Ni3Ln} cubane motifs to afford a rod shaped nano-sized molecule of about 1.2 × 2.8 nm. Unusual MCE behaviour has been found due to multiple low lying excited states arising from competing ferromagnetic and anti-ferromagnetic Ni-Ni and Ni-Ln exchange interactions. © 2016 The Royal Society of Chemistry.
author	Albores, Pablo
author_facet	Albores, Pablo
author_sort	Albores, Pablo
title	{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour
title_short	{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour
title_full	{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour
title_fullStr	{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour
title_full_unstemmed	{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour
title_sort	{ni ii 8 ln iii 6 } (ln = gd, dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable mce behaviour
publishDate	2016
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14779226_v45_n20_p8566_Guarda http://hdl.handle.net/20.500.12110/paper_14779226_v45_n20_p8566_Guarda
work_keys_str_mv	AT alborespablo niii8lniii6lngddyrodlikenanosizedheteronuclearcoordinationclusterswithadoublecarbonatebridgeskeletonandremarkablemcebehaviour
_version_	1768544700232368128

{Ni II 8 Ln III 6 } (Ln = Gd, Dy) rod-like nano-sized heteronuclear coordination clusters with a double carbonate bridge skeleton and remarkable MCE behaviour

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