Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions
Thermal and photochemical stability (ΦR), room temperature UV-vis absorption and fluorescence spectra, fluorescence quantum yields (ΦF) and lifetimes (τF), quantum yields of hydrogen peroxide (ΦH2O2) and singlet oxygen (ΦΔ) production, and triplet lifetimes (τT) have been obtained for the neutral an...
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paper:paper_14639076_v18_n2_p886_RasseSuriani2023-06-08T16:16:29Z Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions Erra Balsells, Rosa harmine hydrogen peroxide oxygen solution and solubility water analogs and derivatives chemical structure chemistry fluorescence photochemistry solution and solubility spectrofluorometry Fluorescence Harmine Hydrogen Peroxide Molecular Structure Oxygen Photochemical Processes Solutions Spectrometry, Fluorescence Water Thermal and photochemical stability (ΦR), room temperature UV-vis absorption and fluorescence spectra, fluorescence quantum yields (ΦF) and lifetimes (τF), quantum yields of hydrogen peroxide (ΦH2O2) and singlet oxygen (ΦΔ) production, and triplet lifetimes (τT) have been obtained for the neutral and protonated forms of 6-chloroharmine, 8-chloroharmine and 6,8-dichloroharmine, in aqueous media. When it was possible, the effect of pH and oxygen concentration was evaluated. The nature of electronic transitions of protonated and neutral species of the three investigated chloroharmines was established using Time-Dependent Density Functional Theory (TD-DFT) calculations. The impact of all the foregoing observations on the biological role of the studied compounds is discussed. © the Owner Societies 2016. Fil:Erra-Balsells, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2015 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v18_n2_p886_RasseSuriani http://hdl.handle.net/20.500.12110/paper_14639076_v18_n2_p886_RasseSuriani |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
harmine hydrogen peroxide oxygen solution and solubility water analogs and derivatives chemical structure chemistry fluorescence photochemistry solution and solubility spectrofluorometry Fluorescence Harmine Hydrogen Peroxide Molecular Structure Oxygen Photochemical Processes Solutions Spectrometry, Fluorescence Water |
spellingShingle |
harmine hydrogen peroxide oxygen solution and solubility water analogs and derivatives chemical structure chemistry fluorescence photochemistry solution and solubility spectrofluorometry Fluorescence Harmine Hydrogen Peroxide Molecular Structure Oxygen Photochemical Processes Solutions Spectrometry, Fluorescence Water Erra Balsells, Rosa Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions |
topic_facet |
harmine hydrogen peroxide oxygen solution and solubility water analogs and derivatives chemical structure chemistry fluorescence photochemistry solution and solubility spectrofluorometry Fluorescence Harmine Hydrogen Peroxide Molecular Structure Oxygen Photochemical Processes Solutions Spectrometry, Fluorescence Water |
description |
Thermal and photochemical stability (ΦR), room temperature UV-vis absorption and fluorescence spectra, fluorescence quantum yields (ΦF) and lifetimes (τF), quantum yields of hydrogen peroxide (ΦH2O2) and singlet oxygen (ΦΔ) production, and triplet lifetimes (τT) have been obtained for the neutral and protonated forms of 6-chloroharmine, 8-chloroharmine and 6,8-dichloroharmine, in aqueous media. When it was possible, the effect of pH and oxygen concentration was evaluated. The nature of electronic transitions of protonated and neutral species of the three investigated chloroharmines was established using Time-Dependent Density Functional Theory (TD-DFT) calculations. The impact of all the foregoing observations on the biological role of the studied compounds is discussed. © the Owner Societies 2016. |
author |
Erra Balsells, Rosa |
author_facet |
Erra Balsells, Rosa |
author_sort |
Erra Balsells, Rosa |
title |
Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions |
title_short |
Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions |
title_full |
Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions |
title_fullStr |
Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions |
title_full_unstemmed |
Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions |
title_sort |
chemical and photochemical properties of chloroharmine derivatives in aqueous solutions |
publishDate |
2015 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14639076_v18_n2_p886_RasseSuriani http://hdl.handle.net/20.500.12110/paper_14639076_v18_n2_p886_RasseSuriani |
work_keys_str_mv |
AT errabalsellsrosa chemicalandphotochemicalpropertiesofchloroharminederivativesinaqueoussolutions |
_version_ |
1768542955208966144 |