Biaryl formation involving carbon-based leaving groups: Why not?

(Chemical Equation Presented) No loss, no gain: In the synthesis of biaryls either the electrophilic or nucleophilic partner can be replaced by a substrate with a carbon-based leaving group (see scheme). Whereas replacing the electrophilic unit is not worthwhile, the use of nucleophiles with a C-bas...

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Detalles Bibliográficos
Publicado:	2008
Materias:	Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v47_n52_p10022_Bonesi http://hdl.handle.net/20.500.12110/paper_14337851_v47_n52_p10022_Bonesi
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_14337851_v47_n52_p10022_Bonesi
record_format	dspace
spelling	paper:paper_14337851_v47_n52_p10022_Bonesi2023-06-08T16:14:19Z Biaryl formation involving carbon-based leaving groups: Why not? Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Arylation Biphenyls C-C activation C-C coupling Leaving groups Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations (Chemical Equation Presented) No loss, no gain: In the synthesis of biaryls either the electrophilic or nucleophilic partner can be replaced by a substrate with a carbon-based leaving group (see scheme). Whereas replacing the electrophilic unit is not worthwhile, the use of nucleophiles with a C-based leaving group has decisive advantages. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA. 2008 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v47_n52_p10022_Bonesi http://hdl.handle.net/20.500.12110/paper_14337851_v47_n52_p10022_Bonesi
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Arylation Biphenyls C-C activation C-C coupling Leaving groups Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations
spellingShingle	Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Arylation Biphenyls C-C activation C-C coupling Leaving groups Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations Biaryl formation involving carbon-based leaving groups: Why not?
topic_facet	Arylation Biphenyls C-C activation C-C coupling Leaving groups Chemical reactions Synthesis (chemical) Arylation Biphenyls C-C activation C-C coupling Leaving groups Aromatic compounds aromatic hydrocarbon biological product bromide carbon carboxylic acid drug methanol chemistry review synthesis Biological Products Bromides Carbon Carboxylic Acids Hydrocarbons, Aromatic Methanol Pharmaceutical Preparations
description	(Chemical Equation Presented) No loss, no gain: In the synthesis of biaryls either the electrophilic or nucleophilic partner can be replaced by a substrate with a carbon-based leaving group (see scheme). Whereas replacing the electrophilic unit is not worthwhile, the use of nucleophiles with a C-based leaving group has decisive advantages. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
title	Biaryl formation involving carbon-based leaving groups: Why not?
title_short	Biaryl formation involving carbon-based leaving groups: Why not?
title_full	Biaryl formation involving carbon-based leaving groups: Why not?
title_fullStr	Biaryl formation involving carbon-based leaving groups: Why not?
title_full_unstemmed	Biaryl formation involving carbon-based leaving groups: Why not?
title_sort	biaryl formation involving carbon-based leaving groups: why not?
publishDate	2008
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_14337851_v47_n52_p10022_Bonesi http://hdl.handle.net/20.500.12110/paper_14337851_v47_n52_p10022_Bonesi
_version_	1768543623861764096

Biaryl formation involving carbon-based leaving groups: Why not?

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