Diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups
Methyl 3-O-acetyl-2-deoxy-α-d-ribofuranoside, 1,3-di-O-acetyl-2-deoxy-α-d-ribofuranose and 1,2,3-tri-O-acetyl-α-d-arabinofuranose were diastereoselectively prepared (de = 100%) from anomeric mixtures of the corresponding 5-acetylated compounds through Candida antarctica B lipase (CAL B)-catalysed al...
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2009
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09574166_v20_n15_p1813_Gudino http://hdl.handle.net/20.500.12110/paper_09574166_v20_n15_p1813_Gudino |
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paper:paper_09574166_v20_n15_p1813_Gudino2023-06-08T15:56:30Z Diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups 1,2,3 tri o acetyl alpha dextro arabinofuranose 1,3 di o acetyl 2 deoxy alpha dextro ribofuranose carbohydrate derivative hydroxyl group lipase B methyl 3 o acetyl 2 deoxy alpha dextro ribofuranoside unclassified drug acetylation alcoholysis article Candida antarctica diastereoisomer enzyme mechanism nonhuman priority journal quantum yield reaction analysis stereochemistry Methyl 3-O-acetyl-2-deoxy-α-d-ribofuranoside, 1,3-di-O-acetyl-2-deoxy-α-d-ribofuranose and 1,2,3-tri-O-acetyl-α-d-arabinofuranose were diastereoselectively prepared (de = 100%) from anomeric mixtures of the corresponding 5-acetylated compounds through Candida antarctica B lipase (CAL B)-catalysed alcoholysis. © 2009 Elsevier Ltd. All rights reserved. 2009 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09574166_v20_n15_p1813_Gudino http://hdl.handle.net/20.500.12110/paper_09574166_v20_n15_p1813_Gudino |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
1,2,3 tri o acetyl alpha dextro arabinofuranose 1,3 di o acetyl 2 deoxy alpha dextro ribofuranose carbohydrate derivative hydroxyl group lipase B methyl 3 o acetyl 2 deoxy alpha dextro ribofuranoside unclassified drug acetylation alcoholysis article Candida antarctica diastereoisomer enzyme mechanism nonhuman priority journal quantum yield reaction analysis stereochemistry |
| spellingShingle |
1,2,3 tri o acetyl alpha dextro arabinofuranose 1,3 di o acetyl 2 deoxy alpha dextro ribofuranose carbohydrate derivative hydroxyl group lipase B methyl 3 o acetyl 2 deoxy alpha dextro ribofuranoside unclassified drug acetylation alcoholysis article Candida antarctica diastereoisomer enzyme mechanism nonhuman priority journal quantum yield reaction analysis stereochemistry Diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups |
| topic_facet |
1,2,3 tri o acetyl alpha dextro arabinofuranose 1,3 di o acetyl 2 deoxy alpha dextro ribofuranose carbohydrate derivative hydroxyl group lipase B methyl 3 o acetyl 2 deoxy alpha dextro ribofuranoside unclassified drug acetylation alcoholysis article Candida antarctica diastereoisomer enzyme mechanism nonhuman priority journal quantum yield reaction analysis stereochemistry |
| description |
Methyl 3-O-acetyl-2-deoxy-α-d-ribofuranoside, 1,3-di-O-acetyl-2-deoxy-α-d-ribofuranose and 1,2,3-tri-O-acetyl-α-d-arabinofuranose were diastereoselectively prepared (de = 100%) from anomeric mixtures of the corresponding 5-acetylated compounds through Candida antarctica B lipase (CAL B)-catalysed alcoholysis. © 2009 Elsevier Ltd. All rights reserved. |
| title |
Diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups |
| title_short |
Diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups |
| title_full |
Diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups |
| title_fullStr |
Diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups |
| title_full_unstemmed |
Diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups |
| title_sort |
diastereoselective enzymatic preparation of acetylated pentofuranosides carrying free 5-hydroxyl groups |
| publishDate |
2009 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09574166_v20_n15_p1813_Gudino http://hdl.handle.net/20.500.12110/paper_09574166_v20_n15_p1813_Gudino |
| _version_ |
1768544001236926464 |