Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene

The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefi...

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Detalles Bibliográficos
Publicado: 1988
Materias:
1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite
CC12CF2, thermal reaction with CF3OF
CF3OF, thermal reaction with CC12CF2
Perfluorobutene-2
Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09429352_v158_nPart_1_p25_DosSantosAfonso
http://hdl.handle.net/20.500.12110/paper_09429352_v158_nPart_1_p25_DosSantosAfonso
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_09429352_v158_nPart_1_p25_DosSantosAfonso
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spelling paper:paper_09429352_v158_nPart_1_p25_DosSantosAfonso2023-06-08T15:53:36Z Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene 1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite CC12CF2, thermal reaction with CF3OF CF3OF, thermal reaction with CC12CF2 Perfluorobutene-2 Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefin, non-volatile condensate appeared. © by R. Oldenbourg Verlag 1988 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09429352_v158_nPart_1_p25_DosSantosAfonso http://hdl.handle.net/20.500.12110/paper_09429352_v158_nPart_1_p25_DosSantosAfonso
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic 1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite
CC12CF2, thermal reaction with CF3OF
CF3OF, thermal reaction with CC12CF2
Perfluorobutene-2
Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene
spellingShingle 1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite
CC12CF2, thermal reaction with CF3OF
CF3OF, thermal reaction with CC12CF2
Perfluorobutene-2
Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene
Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
topic_facet 1,1-Dichlorodifluoroethylene, reaction with trifluoromethylhypofluorite
CC12CF2, thermal reaction with CF3OF
CF3OF, thermal reaction with CC12CF2
Perfluorobutene-2
Trifluoromethylhypofluorite, addition to 1,1-dichlorodifluoroethylene
description The thermal addition of CF3OF to CF2CC12 has been studied between -7.0 and 29.7 °C. The pressure of CF3OF was varied between 6.4 and 196.7 Torr and that of CF2CC12 between 5.4 and 203 Torr. CF3CC12F, CF3o(CF2CC12)F and CF3o(CF2CCl2)1oCF3, where i = 2,3 … n, were the products. Above 110 Torr of olefin, non-volatile condensate appeared. © by R. Oldenbourg Verlag
title Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_short Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_full Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_fullStr Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_full_unstemmed Kinetics and Mechanism of the Thermal Reaction between Trifluoromethylhypofluorite and 1,1-Dichlorodifluoroethylene
title_sort kinetics and mechanism of the thermal reaction between trifluoromethylhypofluorite and 1,1-dichlorodifluoroethylene
publishDate 1988
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09429352_v158_nPart_1_p25_DosSantosAfonso
http://hdl.handle.net/20.500.12110/paper_09429352_v158_nPart_1_p25_DosSantosAfonso
_version_ 1768545700655661056

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