Luminescent Eu(III) hybrid sensors for in situ copper detection

In this work we used the sol-gel technique to develop luminescent Eu(III) transparent films deposited on glass slides to build for sensor devices capable of monitoring transition metal ions in aqueous solutions. The films were obtained from a bis(trialkoxysilyl) organic precursor synthesized from th...

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Autores principales:	Barja, Beatriz Carmen, Bari, Sara Elizabeth, Marchi, María Claudia
Publicado:	2011
Materias:	Cu(II) sensor Europium(III) Hybrid materials Luminescence quenching Sol-gel Aminopropyltriethoxysilane Aqueous media Cetyltrimethylammonium bromide Crosslinker Glass slides In-situ Organic precursor Ppb levels Sensor device Sol-gel technique Stern-Volmer constants Templated Templating agents Transparent films Amides Ammonium compounds Bromine compounds Europium Gels Glass transition Iron compounds Luminescence Metal ions Quenching Silicon compounds Sol-gel process Sol-gels Sols Surface active agents Transition metals Sensors
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09254005_v158_n1_p214_Barja http://hdl.handle.net/20.500.12110/paper_09254005_v158_n1_p214_Barja
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_09254005_v158_n1_p214_Barja
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spelling	paper:paper_09254005_v158_n1_p214_Barja2023-06-08T15:51:16Z Luminescent Eu(III) hybrid sensors for in situ copper detection Barja, Beatriz Carmen Bari, Sara Elizabeth Marchi, María Claudia Cu(II) sensor Europium(III) Hybrid materials Luminescence quenching Sol-gel Aminopropyltriethoxysilane Aqueous media Cetyltrimethylammonium bromide Crosslinker Glass slides In-situ Luminescence quenching Organic precursor Ppb levels Sensor device Sol-gel technique Stern-Volmer constants Templated Templating agents Transparent films Amides Ammonium compounds Bromine compounds Europium Gels Glass transition Hybrid materials Iron compounds Luminescence Metal ions Quenching Silicon compounds Sol-gel process Sol-gels Sols Surface active agents Transition metals Sensors In this work we used the sol-gel technique to develop luminescent Eu(III) transparent films deposited on glass slides to build for sensor devices capable of monitoring transition metal ions in aqueous solutions. The films were obtained from a bis(trialkoxysilyl) organic precursor synthesized from the amide of the 2,6-pyridinedicarboxylic acid (DPA) with aminopropyltriethoxysilane (APTES) in the presence or absence of cetyl trimethyl ammonium bromide (CTAB) surfactant as templating agent and triethylethoxysilane (TEOS) as crosslinker. These sensor devices were used to perform in situ quenching experiments by Cu(II), Fe(III), Co(II) and Ni(II) ions. The results indicate that the templated films allow the detection and quantification of these metals down to ppb levels by means of the values of the Stern-Volmer constants. In particular, it was shown that Cu(II) acts as an extremely efficient quencher (KSV = 3.5 × 105 M-1) when compared with the results obtained for the other metals, opening the possibility to use these devices as potential Cu(II) sensors for actual applications in aqueous media. © 2011 Elsevier B.V. Al rights reserved. Fil:Barja, B.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bari, S.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Marchi, M.C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2011 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09254005_v158_n1_p214_Barja http://hdl.handle.net/20.500.12110/paper_09254005_v158_n1_p214_Barja
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Cu(II) sensor Europium(III) Hybrid materials Luminescence quenching Sol-gel Aminopropyltriethoxysilane Aqueous media Cetyltrimethylammonium bromide Crosslinker Glass slides In-situ Luminescence quenching Organic precursor Ppb levels Sensor device Sol-gel technique Stern-Volmer constants Templated Templating agents Transparent films Amides Ammonium compounds Bromine compounds Europium Gels Glass transition Hybrid materials Iron compounds Luminescence Metal ions Quenching Silicon compounds Sol-gel process Sol-gels Sols Surface active agents Transition metals Sensors
spellingShingle	Cu(II) sensor Europium(III) Hybrid materials Luminescence quenching Sol-gel Aminopropyltriethoxysilane Aqueous media Cetyltrimethylammonium bromide Crosslinker Glass slides In-situ Luminescence quenching Organic precursor Ppb levels Sensor device Sol-gel technique Stern-Volmer constants Templated Templating agents Transparent films Amides Ammonium compounds Bromine compounds Europium Gels Glass transition Hybrid materials Iron compounds Luminescence Metal ions Quenching Silicon compounds Sol-gel process Sol-gels Sols Surface active agents Transition metals Sensors Barja, Beatriz Carmen Bari, Sara Elizabeth Marchi, María Claudia Luminescent Eu(III) hybrid sensors for in situ copper detection
topic_facet	Cu(II) sensor Europium(III) Hybrid materials Luminescence quenching Sol-gel Aminopropyltriethoxysilane Aqueous media Cetyltrimethylammonium bromide Crosslinker Glass slides In-situ Luminescence quenching Organic precursor Ppb levels Sensor device Sol-gel technique Stern-Volmer constants Templated Templating agents Transparent films Amides Ammonium compounds Bromine compounds Europium Gels Glass transition Hybrid materials Iron compounds Luminescence Metal ions Quenching Silicon compounds Sol-gel process Sol-gels Sols Surface active agents Transition metals Sensors
description	In this work we used the sol-gel technique to develop luminescent Eu(III) transparent films deposited on glass slides to build for sensor devices capable of monitoring transition metal ions in aqueous solutions. The films were obtained from a bis(trialkoxysilyl) organic precursor synthesized from the amide of the 2,6-pyridinedicarboxylic acid (DPA) with aminopropyltriethoxysilane (APTES) in the presence or absence of cetyl trimethyl ammonium bromide (CTAB) surfactant as templating agent and triethylethoxysilane (TEOS) as crosslinker. These sensor devices were used to perform in situ quenching experiments by Cu(II), Fe(III), Co(II) and Ni(II) ions. The results indicate that the templated films allow the detection and quantification of these metals down to ppb levels by means of the values of the Stern-Volmer constants. In particular, it was shown that Cu(II) acts as an extremely efficient quencher (KSV = 3.5 × 105 M-1) when compared with the results obtained for the other metals, opening the possibility to use these devices as potential Cu(II) sensors for actual applications in aqueous media. © 2011 Elsevier B.V. Al rights reserved.
author	Barja, Beatriz Carmen Bari, Sara Elizabeth Marchi, María Claudia
author_facet	Barja, Beatriz Carmen Bari, Sara Elizabeth Marchi, María Claudia
author_sort	Barja, Beatriz Carmen
title	Luminescent Eu(III) hybrid sensors for in situ copper detection
title_short	Luminescent Eu(III) hybrid sensors for in situ copper detection
title_full	Luminescent Eu(III) hybrid sensors for in situ copper detection
title_fullStr	Luminescent Eu(III) hybrid sensors for in situ copper detection
title_full_unstemmed	Luminescent Eu(III) hybrid sensors for in situ copper detection
title_sort	luminescent eu(iii) hybrid sensors for in situ copper detection
publishDate	2011
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09254005_v158_n1_p214_Barja http://hdl.handle.net/20.500.12110/paper_09254005_v158_n1_p214_Barja
work_keys_str_mv	AT barjabeatrizcarmen luminescenteuiiihybridsensorsforinsitucopperdetection AT barisaraelizabeth luminescenteuiiihybridsensorsforinsitucopperdetection AT marchimariaclaudia luminescenteuiiihybridsensorsforinsitucopperdetection
_version_	1768545337129041920

Luminescent Eu(III) hybrid sensors for in situ copper detection

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