Effects of aging on the electrical resistivity of La1-xBxCoO3 perovskites (B = Sr, Ca, Ba; 0.20 ≤ x ≤ 0.30)
A study of the reliability of the title compounds as a basis for magnetoresistive sensors is presented. For this purpose we have carried out long-term systematic studies of the evolution of the resistive and magnetic properties of samples synthesized by both ceramic and wet chemical routes, allowing...
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2000
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09244247_v81_n1-3_p23_Mira http://hdl.handle.net/20.500.12110/paper_09244247_v81_n1-3_p23_Mira |
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paper:paper_09244247_v81_n1-3_p23_Mira2023-06-08T15:51:05Z Effects of aging on the electrical resistivity of La1-xBxCoO3 perovskites (B = Sr, Ca, Ba; 0.20 ≤ x ≤ 0.30) Aging effects Magnetoresistance Oxygen stoichiometry Perovskites Aging of materials Electric conductivity of solids Ferromagnetism Lanthanum compounds Magnetic relaxation Magnetoresistance Paramagnetism Perovskite Phase transitions Stoichiometry Synthesis (chemical) Thermal effects Magnetoresistive sensors Reentrant semiconducting behavior Sensors A study of the reliability of the title compounds as a basis for magnetoresistive sensors is presented. For this purpose we have carried out long-term systematic studies of the evolution of the resistive and magnetic properties of samples synthesized by both ceramic and wet chemical routes, allowing them to age during several months. It is observed that, although the magnetic properties remain unaltered, their resistivity does change appreciably. With time, samples that are initially metallic over all the measured temperature range (T < 300 K), change to semiconductor-like behaviour at low temperatures and above their ferromagnetic to paramagnetic phase transition temperature, giving rise to a 'reentrant semiconducting behaviour' with associated high electrical noise, relaxation effects of the resistivity and even diodic behaviour. © 2000 Elsevier Science S.A. All rights reserved. 2000 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09244247_v81_n1-3_p23_Mira http://hdl.handle.net/20.500.12110/paper_09244247_v81_n1-3_p23_Mira |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Aging effects Magnetoresistance Oxygen stoichiometry Perovskites Aging of materials Electric conductivity of solids Ferromagnetism Lanthanum compounds Magnetic relaxation Magnetoresistance Paramagnetism Perovskite Phase transitions Stoichiometry Synthesis (chemical) Thermal effects Magnetoresistive sensors Reentrant semiconducting behavior Sensors |
spellingShingle |
Aging effects Magnetoresistance Oxygen stoichiometry Perovskites Aging of materials Electric conductivity of solids Ferromagnetism Lanthanum compounds Magnetic relaxation Magnetoresistance Paramagnetism Perovskite Phase transitions Stoichiometry Synthesis (chemical) Thermal effects Magnetoresistive sensors Reentrant semiconducting behavior Sensors Effects of aging on the electrical resistivity of La1-xBxCoO3 perovskites (B = Sr, Ca, Ba; 0.20 ≤ x ≤ 0.30) |
topic_facet |
Aging effects Magnetoresistance Oxygen stoichiometry Perovskites Aging of materials Electric conductivity of solids Ferromagnetism Lanthanum compounds Magnetic relaxation Magnetoresistance Paramagnetism Perovskite Phase transitions Stoichiometry Synthesis (chemical) Thermal effects Magnetoresistive sensors Reentrant semiconducting behavior Sensors |
description |
A study of the reliability of the title compounds as a basis for magnetoresistive sensors is presented. For this purpose we have carried out long-term systematic studies of the evolution of the resistive and magnetic properties of samples synthesized by both ceramic and wet chemical routes, allowing them to age during several months. It is observed that, although the magnetic properties remain unaltered, their resistivity does change appreciably. With time, samples that are initially metallic over all the measured temperature range (T < 300 K), change to semiconductor-like behaviour at low temperatures and above their ferromagnetic to paramagnetic phase transition temperature, giving rise to a 'reentrant semiconducting behaviour' with associated high electrical noise, relaxation effects of the resistivity and even diodic behaviour. © 2000 Elsevier Science S.A. All rights reserved. |
title |
Effects of aging on the electrical resistivity of La1-xBxCoO3 perovskites (B = Sr, Ca, Ba; 0.20 ≤ x ≤ 0.30) |
title_short |
Effects of aging on the electrical resistivity of La1-xBxCoO3 perovskites (B = Sr, Ca, Ba; 0.20 ≤ x ≤ 0.30) |
title_full |
Effects of aging on the electrical resistivity of La1-xBxCoO3 perovskites (B = Sr, Ca, Ba; 0.20 ≤ x ≤ 0.30) |
title_fullStr |
Effects of aging on the electrical resistivity of La1-xBxCoO3 perovskites (B = Sr, Ca, Ba; 0.20 ≤ x ≤ 0.30) |
title_full_unstemmed |
Effects of aging on the electrical resistivity of La1-xBxCoO3 perovskites (B = Sr, Ca, Ba; 0.20 ≤ x ≤ 0.30) |
title_sort |
effects of aging on the electrical resistivity of la1-xbxcoo3 perovskites (b = sr, ca, ba; 0.20 ≤ x ≤ 0.30) |
publishDate |
2000 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09244247_v81_n1-3_p23_Mira http://hdl.handle.net/20.500.12110/paper_09244247_v81_n1-3_p23_Mira |
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1768543283507625984 |