Chlorination effects in electrical transport properties of ceramic La2-xSrxCuO4-δ-yCly
We have measured the electrical resistivity ρ{variant}(T) of the chlorinated La2-xSrxCuO4-δ high-Tc superconductor, in a wide range of temperatures (40 ≤ T ≤ 800 K). The systematic effects in ρ{variant}(T) of Cl and Sr contents allowed us, within the Drude and VRH models, to determine the role playe...
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1994
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214534_v227_n3-4_p237_Acha http://hdl.handle.net/20.500.12110/paper_09214534_v227_n3-4_p237_Acha |
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paper:paper_09214534_v227_n3-4_p237_Acha2023-06-08T15:50:41Z Chlorination effects in electrical transport properties of ceramic La2-xSrxCuO4-δ-yCly Acha, Carlos Enrique Bekeris, Victoria Isabel Urba, Laura Gabriela Levy, Pablo Eduardo de la Cruz, Fernando Pablo Ceramic materials Charge carriers Chlorination Composition effects Copper oxides Crystal lattices Doping (additives) Electric conductivity measurement Electron transport properties Lanthanum compounds Order disorder transitions Strontium Drude model Lanthanum strontium copper oxide Lattice parameters VRH model High temperature superconductors We have measured the electrical resistivity ρ{variant}(T) of the chlorinated La2-xSrxCuO4-δ high-Tc superconductor, in a wide range of temperatures (40 ≤ T ≤ 800 K). The systematic effects in ρ{variant}(T) of Cl and Sr contents allowed us, within the Drude and VRH models, to determine the role played by Cl in electrical transport properties: carrier concentration decreases linearly with increasing Cl concentration, and Cl also modifies the electron localized low temperature conducting regime, increasing disorder for low Sr concentration (x = 0.065) while ordering the system for high Sr concentrations (0.08 ≤ x ≤ 0.2). Changes in lattice parameters indicate different structural site occupancies for Cl, depending on Sr doping: for low Sr concentrations an expansion in the c-crystallographic axis with increasing Cl content is observed, while a contraction results for higher Sr contents. © 1994. Fil:Acha, C. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bekeris, V. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Urba, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Levy, P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:de la Cruz, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1994 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214534_v227_n3-4_p237_Acha http://hdl.handle.net/20.500.12110/paper_09214534_v227_n3-4_p237_Acha |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Ceramic materials Charge carriers Chlorination Composition effects Copper oxides Crystal lattices Doping (additives) Electric conductivity measurement Electron transport properties Lanthanum compounds Order disorder transitions Strontium Drude model Lanthanum strontium copper oxide Lattice parameters VRH model High temperature superconductors |
spellingShingle |
Ceramic materials Charge carriers Chlorination Composition effects Copper oxides Crystal lattices Doping (additives) Electric conductivity measurement Electron transport properties Lanthanum compounds Order disorder transitions Strontium Drude model Lanthanum strontium copper oxide Lattice parameters VRH model High temperature superconductors Acha, Carlos Enrique Bekeris, Victoria Isabel Urba, Laura Gabriela Levy, Pablo Eduardo de la Cruz, Fernando Pablo Chlorination effects in electrical transport properties of ceramic La2-xSrxCuO4-δ-yCly |
topic_facet |
Ceramic materials Charge carriers Chlorination Composition effects Copper oxides Crystal lattices Doping (additives) Electric conductivity measurement Electron transport properties Lanthanum compounds Order disorder transitions Strontium Drude model Lanthanum strontium copper oxide Lattice parameters VRH model High temperature superconductors |
description |
We have measured the electrical resistivity ρ{variant}(T) of the chlorinated La2-xSrxCuO4-δ high-Tc superconductor, in a wide range of temperatures (40 ≤ T ≤ 800 K). The systematic effects in ρ{variant}(T) of Cl and Sr contents allowed us, within the Drude and VRH models, to determine the role played by Cl in electrical transport properties: carrier concentration decreases linearly with increasing Cl concentration, and Cl also modifies the electron localized low temperature conducting regime, increasing disorder for low Sr concentration (x = 0.065) while ordering the system for high Sr concentrations (0.08 ≤ x ≤ 0.2). Changes in lattice parameters indicate different structural site occupancies for Cl, depending on Sr doping: for low Sr concentrations an expansion in the c-crystallographic axis with increasing Cl content is observed, while a contraction results for higher Sr contents. © 1994. |
author |
Acha, Carlos Enrique Bekeris, Victoria Isabel Urba, Laura Gabriela Levy, Pablo Eduardo de la Cruz, Fernando Pablo |
author_facet |
Acha, Carlos Enrique Bekeris, Victoria Isabel Urba, Laura Gabriela Levy, Pablo Eduardo de la Cruz, Fernando Pablo |
author_sort |
Acha, Carlos Enrique |
title |
Chlorination effects in electrical transport properties of ceramic La2-xSrxCuO4-δ-yCly |
title_short |
Chlorination effects in electrical transport properties of ceramic La2-xSrxCuO4-δ-yCly |
title_full |
Chlorination effects in electrical transport properties of ceramic La2-xSrxCuO4-δ-yCly |
title_fullStr |
Chlorination effects in electrical transport properties of ceramic La2-xSrxCuO4-δ-yCly |
title_full_unstemmed |
Chlorination effects in electrical transport properties of ceramic La2-xSrxCuO4-δ-yCly |
title_sort |
chlorination effects in electrical transport properties of ceramic la2-xsrxcuo4-δ-ycly |
publishDate |
1994 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214534_v227_n3-4_p237_Acha http://hdl.handle.net/20.500.12110/paper_09214534_v227_n3-4_p237_Acha |
work_keys_str_mv |
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_version_ |
1768542847054643200 |