Phase transformations in Mo-doped FINEMETs

In this paper, the phase transformations occurring during the crystallization process of FINEMETs in which Nb has been gradually replaced by Mo have been studied by a variety of techniques including DSC, DTA, TGA, XRD and TEM. The thermal stability of the alloy was deteriorated as a consequence of M...

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Detalles Bibliográficos
Publicado: 2010
Materias:
TEM
XRD
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v405_n12_p2720_Silveyra
http://hdl.handle.net/20.500.12110/paper_09214526_v405_n12_p2720_Silveyra
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id paper:paper_09214526_v405_n12_p2720_Silveyra
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spelling paper:paper_09214526_v405_n12_p2720_Silveyra2023-06-08T15:50:36Z Phase transformations in Mo-doped FINEMETs FINEMET Phase transformations in amorphous alloys Soft magnetic materials Amorphous phase Atomic sizes Crystallization process FINEMET Onset temperature Phase transformation Phase transformations in amorphous alloys TEM Thermal stability XRD Borides Crystallization Iron alloys Magnetic devices Molybdenum Phase transitions Silicon alloys Soft magnetic materials Thermodynamic stability Amorphous alloys In this paper, the phase transformations occurring during the crystallization process of FINEMETs in which Nb has been gradually replaced by Mo have been studied by a variety of techniques including DSC, DTA, TGA, XRD and TEM. The thermal stability of the alloy was deteriorated as a consequence of Mo's smaller atomic size. The gradual replacement of Nb by Mo reduced the onset temperature of Fe-Si and of the borides. The Curie temperature of the amorphous phase slightly decreased from 594 K for x=0 to 587 K for x=3. The borides compounds Fe2B and Fe23B6 as well as the (Nb,Mo)5Si3 phase were found to precipitate in the second and third crystallization. © 2010 Elsevier B.V. All rights reserved. 2010 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v405_n12_p2720_Silveyra http://hdl.handle.net/20.500.12110/paper_09214526_v405_n12_p2720_Silveyra
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic FINEMET
Phase transformations in amorphous alloys
Soft magnetic materials
Amorphous phase
Atomic sizes
Crystallization process
FINEMET
Onset temperature
Phase transformation
Phase transformations in amorphous alloys
TEM
Thermal stability
XRD
Borides
Crystallization
Iron alloys
Magnetic devices
Molybdenum
Phase transitions
Silicon alloys
Soft magnetic materials
Thermodynamic stability
Amorphous alloys
spellingShingle FINEMET
Phase transformations in amorphous alloys
Soft magnetic materials
Amorphous phase
Atomic sizes
Crystallization process
FINEMET
Onset temperature
Phase transformation
Phase transformations in amorphous alloys
TEM
Thermal stability
XRD
Borides
Crystallization
Iron alloys
Magnetic devices
Molybdenum
Phase transitions
Silicon alloys
Soft magnetic materials
Thermodynamic stability
Amorphous alloys
Phase transformations in Mo-doped FINEMETs
topic_facet FINEMET
Phase transformations in amorphous alloys
Soft magnetic materials
Amorphous phase
Atomic sizes
Crystallization process
FINEMET
Onset temperature
Phase transformation
Phase transformations in amorphous alloys
TEM
Thermal stability
XRD
Borides
Crystallization
Iron alloys
Magnetic devices
Molybdenum
Phase transitions
Silicon alloys
Soft magnetic materials
Thermodynamic stability
Amorphous alloys
description In this paper, the phase transformations occurring during the crystallization process of FINEMETs in which Nb has been gradually replaced by Mo have been studied by a variety of techniques including DSC, DTA, TGA, XRD and TEM. The thermal stability of the alloy was deteriorated as a consequence of Mo's smaller atomic size. The gradual replacement of Nb by Mo reduced the onset temperature of Fe-Si and of the borides. The Curie temperature of the amorphous phase slightly decreased from 594 K for x=0 to 587 K for x=3. The borides compounds Fe2B and Fe23B6 as well as the (Nb,Mo)5Si3 phase were found to precipitate in the second and third crystallization. © 2010 Elsevier B.V. All rights reserved.
title Phase transformations in Mo-doped FINEMETs
title_short Phase transformations in Mo-doped FINEMETs
title_full Phase transformations in Mo-doped FINEMETs
title_fullStr Phase transformations in Mo-doped FINEMETs
title_full_unstemmed Phase transformations in Mo-doped FINEMETs
title_sort phase transformations in mo-doped finemets
publishDate 2010
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09214526_v405_n12_p2720_Silveyra
http://hdl.handle.net/20.500.12110/paper_09214526_v405_n12_p2720_Silveyra
_version_ 1768545793287913472