Enhancement of salicylate photodegradation under bias in binary mixtures

The influence of oxalate and methanol on the photodegradation behaviour of salicylate under bias was studied measuring the time evolution of the photocurrent and the concentration in solution. In N 2 saturated electrolytes, the presence of the second component produces an enhancement of salicylate d...

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Autores principales: Calvo, Mauricio Ernesto, Candal, Roberto Jorge, Aldabe Bilmes, Sara Alfonsina Dora
Publicado: 2002
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v76_n2-4_p133_Calvo
http://hdl.handle.net/20.500.12110/paper_09205861_v76_n2-4_p133_Calvo
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spelling paper:paper_09205861_v76_n2-4_p133_Calvo2025-07-30T18:26:29Z Enhancement of salicylate photodegradation under bias in binary mixtures Calvo, Mauricio Ernesto Candal, Roberto Jorge Aldabe Bilmes, Sara Alfonsina Dora Photocatalysis Photoelectrochemistry Salicylate TiO 2 Binary mixtures Electrolytes Methanol Photocurrents Solutions Photoelectrochemistry Photodegradation The influence of oxalate and methanol on the photodegradation behaviour of salicylate under bias was studied measuring the time evolution of the photocurrent and the concentration in solution. In N 2 saturated electrolytes, the presence of the second component produces an enhancement of salicylate degradation, but the degradation of the added photolyte decreases. In the presence of O 2 or other electron acceptors salicylate photodegradation is faster, and the positive effect of a sacrificial photolyte is minimised. © 2002 Elsevier Science B.V. All rights reserved. Fil:Calvo, M.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Candal, R.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bilmes, S.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2002 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v76_n2-4_p133_Calvo http://hdl.handle.net/20.500.12110/paper_09205861_v76_n2-4_p133_Calvo
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Photocatalysis
Photoelectrochemistry
Salicylate
TiO 2
Binary mixtures
Electrolytes
Methanol
Photocurrents
Solutions
Photoelectrochemistry
Photodegradation
spellingShingle Photocatalysis
Photoelectrochemistry
Salicylate
TiO 2
Binary mixtures
Electrolytes
Methanol
Photocurrents
Solutions
Photoelectrochemistry
Photodegradation
Calvo, Mauricio Ernesto
Candal, Roberto Jorge
Aldabe Bilmes, Sara Alfonsina Dora
Enhancement of salicylate photodegradation under bias in binary mixtures
topic_facet Photocatalysis
Photoelectrochemistry
Salicylate
TiO 2
Binary mixtures
Electrolytes
Methanol
Photocurrents
Solutions
Photoelectrochemistry
Photodegradation
description The influence of oxalate and methanol on the photodegradation behaviour of salicylate under bias was studied measuring the time evolution of the photocurrent and the concentration in solution. In N 2 saturated electrolytes, the presence of the second component produces an enhancement of salicylate degradation, but the degradation of the added photolyte decreases. In the presence of O 2 or other electron acceptors salicylate photodegradation is faster, and the positive effect of a sacrificial photolyte is minimised. © 2002 Elsevier Science B.V. All rights reserved.
author Calvo, Mauricio Ernesto
Candal, Roberto Jorge
Aldabe Bilmes, Sara Alfonsina Dora
author_facet Calvo, Mauricio Ernesto
Candal, Roberto Jorge
Aldabe Bilmes, Sara Alfonsina Dora
author_sort Calvo, Mauricio Ernesto
title Enhancement of salicylate photodegradation under bias in binary mixtures
title_short Enhancement of salicylate photodegradation under bias in binary mixtures
title_full Enhancement of salicylate photodegradation under bias in binary mixtures
title_fullStr Enhancement of salicylate photodegradation under bias in binary mixtures
title_full_unstemmed Enhancement of salicylate photodegradation under bias in binary mixtures
title_sort enhancement of salicylate photodegradation under bias in binary mixtures
publishDate 2002
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v76_n2-4_p133_Calvo
http://hdl.handle.net/20.500.12110/paper_09205861_v76_n2-4_p133_Calvo
work_keys_str_mv AT calvomauricioernesto enhancementofsalicylatephotodegradationunderbiasinbinarymixtures
AT candalrobertojorge enhancementofsalicylatephotodegradationunderbiasinbinarymixtures
AT aldabebilmessaraalfonsinadora enhancementofsalicylatephotodegradationunderbiasinbinarymixtures
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