Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina
The present work explores the hydrogenolysis of glycerol to produce 1,2-propanediol in vapor phase at atmospheric pressure over copper catalysts supported on mesoporous alumina. Catalysts were prepared by alumina impregnation varying CuO loading between 3 wt% and 30 wt%. The textural and structural...
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v296_n_p19_Dieuzeide http://hdl.handle.net/20.500.12110/paper_09205861_v296_n_p19_Dieuzeide |
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paper:paper_09205861_v296_n_p19_Dieuzeide2023-06-08T15:50:13Z Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina Amadeo, Norma Elvira 1,2-propanediol CuO catalysts Glycerol Hydrogenolysis Mesoporous alumina. Alumina Atmospheric pressure Catalysts Copper Copper oxides Glycerol Hydrogenolysis Hydrolysis Mesoporous materials X ray diffraction 1 ,2-propanediol CuO catalyst Mesoporous alumina Non-monotonic dependence Powder X-ray diffraction (pXRD) Structural characteristics Temperature-programmed reduction Textural properties Catalyst supports The present work explores the hydrogenolysis of glycerol to produce 1,2-propanediol in vapor phase at atmospheric pressure over copper catalysts supported on mesoporous alumina. Catalysts were prepared by alumina impregnation varying CuO loading between 3 wt% and 30 wt%. The textural and structural characteristics of the catalysts were determined by N2 sorptometry (BET), powder X-ray diffraction (PXRD), temperature programmed reduction (TPR) and N2O chemisorption (copper metallic area). The characterization showed that all catalysts present textural properties characteristic of mesoporous solids, such as the adsorption isotherms which are type IV. Based both on characterization and activity results, it was possible to conclude that the yield to 1,2-propanediol presented a non-monotonic dependence on total copper metallic area. In addition, it was proved that 1,2-propanediol production is associated with the presence of highly dispersed CuO phase in the solids. Promising results were obtained with CuO(15)Al catalysts, taking into account that the performance can be improved by increasing residence time. © 2017 Elsevier B.V. Fil:Amadeo, N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2017 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v296_n_p19_Dieuzeide http://hdl.handle.net/20.500.12110/paper_09205861_v296_n_p19_Dieuzeide |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
1,2-propanediol CuO catalysts Glycerol Hydrogenolysis Mesoporous alumina. Alumina Atmospheric pressure Catalysts Copper Copper oxides Glycerol Hydrogenolysis Hydrolysis Mesoporous materials X ray diffraction 1 ,2-propanediol CuO catalyst Mesoporous alumina Non-monotonic dependence Powder X-ray diffraction (pXRD) Structural characteristics Temperature-programmed reduction Textural properties Catalyst supports |
spellingShingle |
1,2-propanediol CuO catalysts Glycerol Hydrogenolysis Mesoporous alumina. Alumina Atmospheric pressure Catalysts Copper Copper oxides Glycerol Hydrogenolysis Hydrolysis Mesoporous materials X ray diffraction 1 ,2-propanediol CuO catalyst Mesoporous alumina Non-monotonic dependence Powder X-ray diffraction (pXRD) Structural characteristics Temperature-programmed reduction Textural properties Catalyst supports Amadeo, Norma Elvira Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina |
topic_facet |
1,2-propanediol CuO catalysts Glycerol Hydrogenolysis Mesoporous alumina. Alumina Atmospheric pressure Catalysts Copper Copper oxides Glycerol Hydrogenolysis Hydrolysis Mesoporous materials X ray diffraction 1 ,2-propanediol CuO catalyst Mesoporous alumina Non-monotonic dependence Powder X-ray diffraction (pXRD) Structural characteristics Temperature-programmed reduction Textural properties Catalyst supports |
description |
The present work explores the hydrogenolysis of glycerol to produce 1,2-propanediol in vapor phase at atmospheric pressure over copper catalysts supported on mesoporous alumina. Catalysts were prepared by alumina impregnation varying CuO loading between 3 wt% and 30 wt%. The textural and structural characteristics of the catalysts were determined by N2 sorptometry (BET), powder X-ray diffraction (PXRD), temperature programmed reduction (TPR) and N2O chemisorption (copper metallic area). The characterization showed that all catalysts present textural properties characteristic of mesoporous solids, such as the adsorption isotherms which are type IV. Based both on characterization and activity results, it was possible to conclude that the yield to 1,2-propanediol presented a non-monotonic dependence on total copper metallic area. In addition, it was proved that 1,2-propanediol production is associated with the presence of highly dispersed CuO phase in the solids. Promising results were obtained with CuO(15)Al catalysts, taking into account that the performance can be improved by increasing residence time. © 2017 Elsevier B.V. |
author |
Amadeo, Norma Elvira |
author_facet |
Amadeo, Norma Elvira |
author_sort |
Amadeo, Norma Elvira |
title |
Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina |
title_short |
Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina |
title_full |
Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina |
title_fullStr |
Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina |
title_full_unstemmed |
Vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina |
title_sort |
vapor phase hydrogenolysis of glycerol to 1,2-propanediol at atmospheric pressure over copper catalysts supported on mesoporous alumina |
publishDate |
2017 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_09205861_v296_n_p19_Dieuzeide http://hdl.handle.net/20.500.12110/paper_09205861_v296_n_p19_Dieuzeide |
work_keys_str_mv |
AT amadeonormaelvira vaporphasehydrogenolysisofglycerolto12propanediolatatmosphericpressureovercoppercatalystssupportedonmesoporousalumina |
_version_ |
1768545516374720512 |