Cure temperature influence on natural Rubber - A small angle X-ray scattering study

To analyze the natural rubber behavior during vulcanization under different cure treatments, an experimental investigation using small angle X-ray scattering was performed. To achieve this, a set of samples were prepared using sulfur and N-t-butyl-2-benzothiazole sulfonamide as accelerator and then...

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Detalles Bibliográficos
Publicado:	2007
Materias:	Natural rubber Small angle X-ray scattering (SAXS) Vulcanization process Crosslinking Mechanical properties Rheometers Sulfur Thermal effects Vulcanization X ray scattering Cure temperature Rheometer tests Swelling techniques Rubber
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08876266_v45_n21_p2966_Salgueiro http://hdl.handle.net/20.500.12110/paper_08876266_v45_n21_p2966_Salgueiro
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_08876266_v45_n21_p2966_Salgueiro
record_format	dspace
spelling	paper:paper_08876266_v45_n21_p2966_Salgueiro2023-06-08T15:46:55Z Cure temperature influence on natural Rubber - A small angle X-ray scattering study Natural rubber Small angle X-ray scattering (SAXS) Vulcanization process Crosslinking Mechanical properties Rheometers Sulfur Thermal effects Vulcanization X ray scattering Cure temperature Rheometer tests Swelling techniques Vulcanization process Rubber To analyze the natural rubber behavior during vulcanization under different cure treatments, an experimental investigation using small angle X-ray scattering was performed. To achieve this, a set of samples were prepared using sulfur and N-t-butyl-2-benzothiazole sulfonamide as accelerator and then cured at temperatures between 403 and 463 K reaching their optimum mechanical properties considering rheometer tests. The crosslink density of the samples was evaluated by means of the swelling technique in solvent. In the usual Lorentz corrected representation of the Xray scattered intensity, a maximum was observed in the plots corresponding to the cured samples, revealing a highly correlated structure. This maximum shifted toward higher values of the scattering vector when the cure temperature of the samples increased. This behavior is discussed in terms of the crosslinks type present in the vulcanized rubber network at different cure temperatures. © 2007 Wiley Periodicals, Inc. 2007 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08876266_v45_n21_p2966_Salgueiro http://hdl.handle.net/20.500.12110/paper_08876266_v45_n21_p2966_Salgueiro
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Natural rubber Small angle X-ray scattering (SAXS) Vulcanization process Crosslinking Mechanical properties Rheometers Sulfur Thermal effects Vulcanization X ray scattering Cure temperature Rheometer tests Swelling techniques Vulcanization process Rubber
spellingShingle	Natural rubber Small angle X-ray scattering (SAXS) Vulcanization process Crosslinking Mechanical properties Rheometers Sulfur Thermal effects Vulcanization X ray scattering Cure temperature Rheometer tests Swelling techniques Vulcanization process Rubber Cure temperature influence on natural Rubber - A small angle X-ray scattering study
topic_facet	Natural rubber Small angle X-ray scattering (SAXS) Vulcanization process Crosslinking Mechanical properties Rheometers Sulfur Thermal effects Vulcanization X ray scattering Cure temperature Rheometer tests Swelling techniques Vulcanization process Rubber
description	To analyze the natural rubber behavior during vulcanization under different cure treatments, an experimental investigation using small angle X-ray scattering was performed. To achieve this, a set of samples were prepared using sulfur and N-t-butyl-2-benzothiazole sulfonamide as accelerator and then cured at temperatures between 403 and 463 K reaching their optimum mechanical properties considering rheometer tests. The crosslink density of the samples was evaluated by means of the swelling technique in solvent. In the usual Lorentz corrected representation of the Xray scattered intensity, a maximum was observed in the plots corresponding to the cured samples, revealing a highly correlated structure. This maximum shifted toward higher values of the scattering vector when the cure temperature of the samples increased. This behavior is discussed in terms of the crosslinks type present in the vulcanized rubber network at different cure temperatures. © 2007 Wiley Periodicals, Inc.
title	Cure temperature influence on natural Rubber - A small angle X-ray scattering study
title_short	Cure temperature influence on natural Rubber - A small angle X-ray scattering study
title_full	Cure temperature influence on natural Rubber - A small angle X-ray scattering study
title_fullStr	Cure temperature influence on natural Rubber - A small angle X-ray scattering study
title_full_unstemmed	Cure temperature influence on natural Rubber - A small angle X-ray scattering study
title_sort	cure temperature influence on natural rubber - a small angle x-ray scattering study
publishDate	2007
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_08876266_v45_n21_p2966_Salgueiro http://hdl.handle.net/20.500.12110/paper_08876266_v45_n21_p2966_Salgueiro
_version_	1768545335643209728

Cure temperature influence on natural Rubber - A small angle X-ray scattering study

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