Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants

Configurational assignment and conformational analysis of a series of iminodihydrofurans obtained from cyanoacetylenic alcohols were performed on the basis of experimental measurements and high-level ab initio calculations of their 13C-13C spin-spin coupling constants. The title compounds were shown...

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Publicado:	2007
Materias:	13C NMR Configurational assignment Conformational analysis Iminodihydrofurans NMR SOPPA Spin-spin coupling constant alcohol derivative furan derivative imine algorithm article chemical structure chemistry conformation isomerism nuclear magnetic resonance spectroscopy Alcohols Algorithms Furans Imines Isomerism Magnetic Resonance Spectroscopy Models, Molecular Molecular Conformation
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v45_n9_p758_Krivdin http://hdl.handle.net/20.500.12110/paper_07491581_v45_n9_p758_Krivdin
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_07491581_v45_n9_p758_Krivdin
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spelling	paper:paper_07491581_v45_n9_p758_Krivdin2023-06-08T15:45:36Z Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants 13C NMR Configurational assignment Conformational analysis Iminodihydrofurans NMR SOPPA Spin-spin coupling constant alcohol derivative furan derivative imine algorithm article chemical structure chemistry conformation isomerism nuclear magnetic resonance spectroscopy Alcohols Algorithms Furans Imines Isomerism Magnetic Resonance Spectroscopy Models, Molecular Molecular Conformation Configurational assignment and conformational analysis of a series of iminodihydrofurans obtained from cyanoacetylenic alcohols were performed on the basis of experimental measurements and high-level ab initio calculations of their 13C-13C spin-spin coupling constants. The title compounds were shown to form and exist in solution as the individual Z isomers, adopting the orthogonal orientation of the amino, alkylamino and dialkylamino groups and the s-trans orientation of the CONH2 group at the C 4 position of the 2,5-dihydro-2-iminofuran moiety. Copyright © 2007 John Wiley & Sons, Ltd. 2007 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v45_n9_p758_Krivdin http://hdl.handle.net/20.500.12110/paper_07491581_v45_n9_p758_Krivdin
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	13C NMR Configurational assignment Conformational analysis Iminodihydrofurans NMR SOPPA Spin-spin coupling constant alcohol derivative furan derivative imine algorithm article chemical structure chemistry conformation isomerism nuclear magnetic resonance spectroscopy Alcohols Algorithms Furans Imines Isomerism Magnetic Resonance Spectroscopy Models, Molecular Molecular Conformation
spellingShingle	13C NMR Configurational assignment Conformational analysis Iminodihydrofurans NMR SOPPA Spin-spin coupling constant alcohol derivative furan derivative imine algorithm article chemical structure chemistry conformation isomerism nuclear magnetic resonance spectroscopy Alcohols Algorithms Furans Imines Isomerism Magnetic Resonance Spectroscopy Models, Molecular Molecular Conformation Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants
topic_facet	13C NMR Configurational assignment Conformational analysis Iminodihydrofurans NMR SOPPA Spin-spin coupling constant alcohol derivative furan derivative imine algorithm article chemical structure chemistry conformation isomerism nuclear magnetic resonance spectroscopy Alcohols Algorithms Furans Imines Isomerism Magnetic Resonance Spectroscopy Models, Molecular Molecular Conformation
description	Configurational assignment and conformational analysis of a series of iminodihydrofurans obtained from cyanoacetylenic alcohols were performed on the basis of experimental measurements and high-level ab initio calculations of their 13C-13C spin-spin coupling constants. The title compounds were shown to form and exist in solution as the individual Z isomers, adopting the orthogonal orientation of the amino, alkylamino and dialkylamino groups and the s-trans orientation of the CONH2 group at the C 4 position of the 2,5-dihydro-2-iminofuran moiety. Copyright © 2007 John Wiley & Sons, Ltd.
title	Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants
title_short	Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants
title_full	Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants
title_fullStr	Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants
title_full_unstemmed	Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants
title_sort	stereochemical study of iminodihydrofurans based on experimental measurements and soppa calculations of13c-13c spin-spin coupling constants
publishDate	2007
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v45_n9_p758_Krivdin http://hdl.handle.net/20.500.12110/paper_07491581_v45_n9_p758_Krivdin
_version_	1768545790560567296

Stereochemical study of iminodihydrofurans based on experimental measurements and SOPPA calculations of13C-13C spin-spin coupling constants

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