13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers
The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley &a...
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1988
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v26_n7_p539_Doller http://hdl.handle.net/20.500.12110/paper_07491581_v26_n7_p539_Doller |
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paper:paper_07491581_v26_n7_p539_Doller2023-06-08T15:45:27Z 13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers Doller, Darío Gros, Eduardo Gervasio 13C NMR spectra 3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one 3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one Acid‐catalysed rearrangement The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley & Sons, Ltd. Fil:Doller, D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1988 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v26_n7_p539_Doller http://hdl.handle.net/20.500.12110/paper_07491581_v26_n7_p539_Doller |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
13C NMR spectra 3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one 3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one Acid‐catalysed rearrangement |
| spellingShingle |
13C NMR spectra 3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one 3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one Acid‐catalysed rearrangement Doller, Darío Gros, Eduardo Gervasio 13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers |
| topic_facet |
13C NMR spectra 3β, 16β‐Dihydroxy‐androst‐5‐en‐17‐one 3β, 17β‐Dihydroxy‐androst‐5‐en‐16‐one Acid‐catalysed rearrangement |
| description |
The acid‐catalysed rearrangement of 3β, 16β‐dihydroxyandrost‐5‐en‐17‐one to 3β, 17β‐dihydroxyandrost‐5‐en‐16‐one was studied by 13C NMR spectroscopy. The spectra indicated that the reaction is produced by an intramolecular 1, 2‐shift of hydride from C‐16α to C‐17α. Copyright © 1988 John Wiley & Sons, Ltd. |
| author |
Doller, Darío Gros, Eduardo Gervasio |
| author_facet |
Doller, Darío Gros, Eduardo Gervasio |
| author_sort |
Doller, Darío |
| title |
13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers |
| title_short |
13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers |
| title_full |
13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers |
| title_fullStr |
13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers |
| title_full_unstemmed |
13C NMR spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers |
| title_sort |
13c nmr spectroscopic study of the rearrangement of 16β‐hydroxy‐17‐oxo steroids to 17β‐hydroxy‐16‐oxo isomers |
| publishDate |
1988 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07491581_v26_n7_p539_Doller http://hdl.handle.net/20.500.12110/paper_07491581_v26_n7_p539_Doller |
| work_keys_str_mv |
AT dollerdario 13cnmrspectroscopicstudyoftherearrangementof16bhydroxy17oxosteroidsto17bhydroxy16oxoisomers AT groseduardogervasio 13cnmrspectroscopicstudyoftherearrangementof16bhydroxy17oxosteroidsto17bhydroxy16oxoisomers |
| _version_ |
1768545335074881536 |