Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy

The Zemplén degradation of 2, 3, 5, 6, 2’, 3’, 4’, 6’-octa-0-benzoylcellobi-ononitrile (1), -lactobiononitrile (2), and -maltobiononitrile (3) was carried out giving a mixture of the four 3-0-(D-hexopyranosyl)-D-arabinoses. Their reduction gave the 3-O-(D-hexopyranosyl)-D-arabinitols, and their benz...

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Detalles Bibliográficos
Autores principales:	D'Accorso, Norma Beatriz, Thiel, Inge María E.
Publicado:	1989
Materias:	arabinitol derivative unclassified drug article drug structure drug synthesis nonhuman nuclear magnetic resonance
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v8_n5_p743_DAccorso http://hdl.handle.net/20.500.12110/paper_07328303_v8_n5_p743_DAccorso
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_07328303_v8_n5_p743_DAccorso
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spelling	paper:paper_07328303_v8_n5_p743_DAccorso2023-06-08T15:43:59Z Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy D'Accorso, Norma Beatriz Thiel, Inge María E. arabinitol derivative unclassified drug article drug structure drug synthesis nonhuman nuclear magnetic resonance The Zemplén degradation of 2, 3, 5, 6, 2’, 3’, 4’, 6’-octa-0-benzoylcellobi-ononitrile (1), -lactobiononitrile (2), and -maltobiononitrile (3) was carried out giving a mixture of the four 3-0-(D-hexopyranosyl)-D-arabinoses. Their reduction gave the 3-O-(D-hexopyranosyl)-D-arabinitols, and their benzoylation gave the 1, 2, 4, 5, 2’, 3’, 4’, 6’-octa-O-benzoyl-(D-hexopyranosyl)-D-arabinitols. Their 1 H and 13 C NMR spectra are described, and their conformations are determined to be planar zig-zag for the acyclic moieties. © 1989, Taylor & Francis Group, LLC. All rights reserved. Fil:D'Accorso, N.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Thiel, I.M.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1989 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v8_n5_p743_DAccorso http://hdl.handle.net/20.500.12110/paper_07328303_v8_n5_p743_DAccorso
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	arabinitol derivative unclassified drug article drug structure drug synthesis nonhuman nuclear magnetic resonance
spellingShingle	arabinitol derivative unclassified drug article drug structure drug synthesis nonhuman nuclear magnetic resonance D'Accorso, Norma Beatriz Thiel, Inge María E. Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy
topic_facet	arabinitol derivative unclassified drug article drug structure drug synthesis nonhuman nuclear magnetic resonance
description	The Zemplén degradation of 2, 3, 5, 6, 2’, 3’, 4’, 6’-octa-0-benzoylcellobi-ononitrile (1), -lactobiononitrile (2), and -maltobiononitrile (3) was carried out giving a mixture of the four 3-0-(D-hexopyranosyl)-D-arabinoses. Their reduction gave the 3-O-(D-hexopyranosyl)-D-arabinitols, and their benzoylation gave the 1, 2, 4, 5, 2’, 3’, 4’, 6’-octa-O-benzoyl-(D-hexopyranosyl)-D-arabinitols. Their 1 H and 13 C NMR spectra are described, and their conformations are determined to be planar zig-zag for the acyclic moieties. © 1989, Taylor & Francis Group, LLC. All rights reserved.
author	D'Accorso, Norma Beatriz Thiel, Inge María E.
author_facet	D'Accorso, Norma Beatriz Thiel, Inge María E.
author_sort	D'Accorso, Norma Beatriz
title	Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy
title_short	Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy
title_full	Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy
title_fullStr	Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy
title_full_unstemmed	Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy
title_sort	degradation of some octa-o-benzoylaldobiononitriles: studies of the products by nmr spectroscopy
publishDate	1989
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v8_n5_p743_DAccorso http://hdl.handle.net/20.500.12110/paper_07328303_v8_n5_p743_DAccorso
work_keys_str_mv	AT daccorsonormabeatriz degradationofsomeoctaobenzoylaldobiononitrilesstudiesoftheproductsbynmrspectroscopy AT thielingemariae degradationofsomeoctaobenzoylaldobiononitrilesstudiesoftheproductsbynmrspectroscopy
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Degradation of Some Octa-O-Benzoylaldobiononitriles: Studies of The Products by NMR Spectroscopy

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