The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium

In contrast with the spectra previously measured with lower resolution equipment, the 500-MHz 1H NMR spectra of l, l-bis(acetam1do)-1-deoxy-D-gl ucitol peracetate and N-acetyl-α-D-galactopyranosylamine peracetate in aqueous solution were amenable to full resolution. The former compound shows a “sick...

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Publicado: 1987
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v6_n3_p515_Matulewicz
http://hdl.handle.net/20.500.12110/paper_07328303_v6_n3_p515_Matulewicz
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_07328303_v6_n3_p515_Matulewicz
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spelling paper:paper_07328303_v6_n3_p515_Matulewicz2023-06-08T15:43:59Z The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium In contrast with the spectra previously measured with lower resolution equipment, the 500-MHz 1H NMR spectra of l, l-bis(acetam1do)-1-deoxy-D-gl ucitol peracetate and N-acetyl-α-D-galactopyranosylamine peracetate in aqueous solution were amenable to full resolution. The former compound shows a “sickle” conformation produced by rotation of the C2–C3 bond out of the planar, zigzag arrangement, while the latter has a 4C1conformation. © 1987, Taylor & Francis Group, LLC. All rights reserved. 1987 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v6_n3_p515_Matulewicz http://hdl.handle.net/20.500.12110/paper_07328303_v6_n3_p515_Matulewicz
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description In contrast with the spectra previously measured with lower resolution equipment, the 500-MHz 1H NMR spectra of l, l-bis(acetam1do)-1-deoxy-D-gl ucitol peracetate and N-acetyl-α-D-galactopyranosylamine peracetate in aqueous solution were amenable to full resolution. The former compound shows a “sickle” conformation produced by rotation of the C2–C3 bond out of the planar, zigzag arrangement, while the latter has a 4C1conformation. © 1987, Taylor & Francis Group, LLC. All rights reserved.
title The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
spellingShingle The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_short The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_full The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_fullStr The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_full_unstemmed The high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
title_sort high-resolution 1h nmr spectra and conformations of n-acetyl-α-d-galactopyranosylamine peracetate and 1, 1-bis(acetamido)-l-deoxy-d-glucitol peracetate in aqueous medium
publishDate 1987
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v6_n3_p515_Matulewicz
http://hdl.handle.net/20.500.12110/paper_07328303_v6_n3_p515_Matulewicz
_version_ 1768542224046358528

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