Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose

The stereospecific synthesis of methyl 3-0-benzoyl-6-0-(tert-butyldiphenylsilyl)-2-deoxy-a-D-e/j//iro-hexopyranosid-4-ulose (5) - a Thromboxane B2 (TXB2) precursor - starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a s...

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Autor principal: Moradei, Oscar Miguel
Publicado: 1995
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v14_n4-5_p525_Moradei
http://hdl.handle.net/20.500.12110/paper_07328303_v14_n4-5_p525_Moradei
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_07328303_v14_n4-5_p525_Moradei
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spelling paper:paper_07328303_v14_n4-5_p525_Moradei2023-06-08T15:43:55Z Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose Moradei, Oscar Miguel The stereospecific synthesis of methyl 3-0-benzoyl-6-0-(tert-butyldiphenylsilyl)-2-deoxy-a-D-e/j//iro-hexopyranosid-4-ulose (5) - a Thromboxane B2 (TXB2) precursor - starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a stereocontrolled hydrogenation (Pd /charcoal) were employed effectively. © 1995, Taylor & Francis Group, LLC. All rights reserved. Fil:Moradei, O. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1995 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v14_n4-5_p525_Moradei http://hdl.handle.net/20.500.12110/paper_07328303_v14_n4-5_p525_Moradei
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The stereospecific synthesis of methyl 3-0-benzoyl-6-0-(tert-butyldiphenylsilyl)-2-deoxy-a-D-e/j//iro-hexopyranosid-4-ulose (5) - a Thromboxane B2 (TXB2) precursor - starting from D-galactose is described. Facile and established methods including selective benzoylation, oxidation-elimination and a stereocontrolled hydrogenation (Pd /charcoal) were employed effectively. © 1995, Taylor & Francis Group, LLC. All rights reserved.
author Moradei, Oscar Miguel
spellingShingle Moradei, Oscar Miguel
Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
author_facet Moradei, Oscar Miguel
author_sort Moradei, Oscar Miguel
title Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_short Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_full Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_fullStr Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_full_unstemmed Simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane B2 (txb2) precursors, from d-galactose
title_sort simple stereocontrolled synthesis of methyl 2-deoxy-d-£/mffl(?-hexopyranosid-4-uloses, thromboxane b2 (txb2) precursors, from d-galactose
publishDate 1995
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_07328303_v14_n4-5_p525_Moradei
http://hdl.handle.net/20.500.12110/paper_07328303_v14_n4-5_p525_Moradei
work_keys_str_mv AT moradeioscarmiguel simplestereocontrolledsynthesisofmethyl2deoxydmfflhexopyranosid4ulosesthromboxaneb2txb2precursorsfromdgalactose
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