Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine
The preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine was accomplished by oxydation of the unlabelled compound to tomatidone, exchange of the labile hydrogens by reaction with H20 and 3H2O on basic alumina and direct reduction of the labelled tomatidone to tomatidine. The efficiency of the procedure...
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1986
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03624803_v23_n1_p109_Doller http://hdl.handle.net/20.500.12110/paper_03624803_v23_n1_p109_Doller |
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paper:paper_03624803_v23_n1_p109_Doller2023-06-08T15:35:09Z Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine Doller, Darío Gros, Eduardo Gervasio |2,4‐2H|‐Tomatidine |2,4‐3H|‐Tomatidine radioisotope methodology nonhuman priority journal theoretical study tomatidine h 2 tomatidine h 3 The preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine was accomplished by oxydation of the unlabelled compound to tomatidone, exchange of the labile hydrogens by reaction with H20 and 3H2O on basic alumina and direct reduction of the labelled tomatidone to tomatidine. The efficiency of the procedure was checked by physical (1H and 13C NMR, MS) methods. Copyright © 1986 John Wiley & Sons, Ltd. Fil:Doller, D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1986 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03624803_v23_n1_p109_Doller http://hdl.handle.net/20.500.12110/paper_03624803_v23_n1_p109_Doller |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
|2,4‐2H|‐Tomatidine |2,4‐3H|‐Tomatidine radioisotope methodology nonhuman priority journal theoretical study tomatidine h 2 tomatidine h 3 |
| spellingShingle |
|2,4‐2H|‐Tomatidine |2,4‐3H|‐Tomatidine radioisotope methodology nonhuman priority journal theoretical study tomatidine h 2 tomatidine h 3 Doller, Darío Gros, Eduardo Gervasio Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| topic_facet |
|2,4‐2H|‐Tomatidine |2,4‐3H|‐Tomatidine radioisotope methodology nonhuman priority journal theoretical study tomatidine h 2 tomatidine h 3 |
| description |
The preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine was accomplished by oxydation of the unlabelled compound to tomatidone, exchange of the labile hydrogens by reaction with H20 and 3H2O on basic alumina and direct reduction of the labelled tomatidone to tomatidine. The efficiency of the procedure was checked by physical (1H and 13C NMR, MS) methods. Copyright © 1986 John Wiley & Sons, Ltd. |
| author |
Doller, Darío Gros, Eduardo Gervasio |
| author_facet |
Doller, Darío Gros, Eduardo Gervasio |
| author_sort |
Doller, Darío |
| title |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_short |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_full |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_fullStr |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_full_unstemmed |
Preparation of |2,4‐2H|‐ and |2,4‐3H|‐tomatidine |
| title_sort |
preparation of |2,4‐2h|‐ and |2,4‐3h|‐tomatidine |
| publishDate |
1986 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03624803_v23_n1_p109_Doller http://hdl.handle.net/20.500.12110/paper_03624803_v23_n1_p109_Doller |
| work_keys_str_mv |
AT dollerdario preparationof242hand243htomatidine AT groseduardogervasio preparationof242hand243htomatidine |
| _version_ |
1768543423810240512 |