Oxidation of sulfur dioxide in a slurry reactor
Adsorption and reaction studies were carried out for the catalytic oxidation of sulfur dioxide in a slurry reactor, using activated carbon as catalyst, at room temperature and atmospheric pressure. It was verified that the rate is first order in oxygen and zero order in sulfur dioxide. The reaction...
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1989
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009467_v41_n1_p1_Amadeo http://hdl.handle.net/20.500.12110/paper_03009467_v41_n1_p1_Amadeo |
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paper:paper_03009467_v41_n1_p1_Amadeo2023-06-08T15:27:38Z Oxidation of sulfur dioxide in a slurry reactor Carbon--Activated Catalysts--Activated Carbon Chemical Equipment--Reactors Mass Transfer Bubbling Nozzle Slurry Reactor Sulfur Dioxide Adsorption and reaction studies were carried out for the catalytic oxidation of sulfur dioxide in a slurry reactor, using activated carbon as catalyst, at room temperature and atmospheric pressure. It was verified that the rate is first order in oxygen and zero order in sulfur dioxide. The reaction rate is controlled by gas-liquid mass transfer and by diffusion and reaction in the catalyst particles. The contribution of each step varies with the operative conditions such as particle diameter, stirring rate, type of distributor and catalyst load. Internal diffusion resistance in the particle is significant; the effectiveness factor is less than 0.9 even for particles of about 0.006 cm diameter. © 1989. 1989 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009467_v41_n1_p1_Amadeo http://hdl.handle.net/20.500.12110/paper_03009467_v41_n1_p1_Amadeo |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Carbon--Activated Catalysts--Activated Carbon Chemical Equipment--Reactors Mass Transfer Bubbling Nozzle Slurry Reactor Sulfur Dioxide |
spellingShingle |
Carbon--Activated Catalysts--Activated Carbon Chemical Equipment--Reactors Mass Transfer Bubbling Nozzle Slurry Reactor Sulfur Dioxide Oxidation of sulfur dioxide in a slurry reactor |
topic_facet |
Carbon--Activated Catalysts--Activated Carbon Chemical Equipment--Reactors Mass Transfer Bubbling Nozzle Slurry Reactor Sulfur Dioxide |
description |
Adsorption and reaction studies were carried out for the catalytic oxidation of sulfur dioxide in a slurry reactor, using activated carbon as catalyst, at room temperature and atmospheric pressure. It was verified that the rate is first order in oxygen and zero order in sulfur dioxide. The reaction rate is controlled by gas-liquid mass transfer and by diffusion and reaction in the catalyst particles. The contribution of each step varies with the operative conditions such as particle diameter, stirring rate, type of distributor and catalyst load. Internal diffusion resistance in the particle is significant; the effectiveness factor is less than 0.9 even for particles of about 0.006 cm diameter. © 1989. |
title |
Oxidation of sulfur dioxide in a slurry reactor |
title_short |
Oxidation of sulfur dioxide in a slurry reactor |
title_full |
Oxidation of sulfur dioxide in a slurry reactor |
title_fullStr |
Oxidation of sulfur dioxide in a slurry reactor |
title_full_unstemmed |
Oxidation of sulfur dioxide in a slurry reactor |
title_sort |
oxidation of sulfur dioxide in a slurry reactor |
publishDate |
1989 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_03009467_v41_n1_p1_Amadeo http://hdl.handle.net/20.500.12110/paper_03009467_v41_n1_p1_Amadeo |
_version_ |
1768543845405949952 |