Substitution kinetics in the complexes of pentacyanoruthenate(II) with ethylenediamine
The salt Na3[Ru(CN)5(en)]·2H2O (en = ethylenediamine) has been prepared and characterized by its IR and electronic spectral properties. The dissociation rate constant, k-L, was found to be dependent on pH, as expected from the protonation of the unbound N-site of the en ligand. From the values of k-...
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Autor principal: | Olabe Iparraguirre, Jose Antonio |
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Publicado: |
1989
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v8_n17_p2091_Tokman http://hdl.handle.net/20.500.12110/paper_02775387_v8_n17_p2091_Tokman |
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