Preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(II) with hydrazine

Potassium pentacyanohydrazineruthenate(II) trihydrate has been synthesized and characterized by chemical methods, IR and electronic spectroscopy. The specific rate constants for the formation, kL, and dissociation, k-L, reactions of the [Ru(CN)5L]n- ions (L = N2H4, N2H5 +) were obtained, as well as...

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Autor principal: Olabe Iparraguirre, Jose Antonio
Publicado: 1992
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v11_n10_p1229_Chevalier
http://hdl.handle.net/20.500.12110/paper_02775387_v11_n10_p1229_Chevalier
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paper:paper_02775387_v11_n10_p1229_Chevalier2023-06-08T15:26:04Z Preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(II) with hydrazine Olabe Iparraguirre, Jose Antonio Potassium pentacyanohydrazineruthenate(II) trihydrate has been synthesized and characterized by chemical methods, IR and electronic spectroscopy. The specific rate constants for the formation, kL, and dissociation, k-L, reactions of the [Ru(CN)5L]n- ions (L = N2H4, N2H5 +) were obtained, as well as the corresponding stability constants, KL. A value of pKa for the bonded N2H5 + species was also calculated. The results were interpreted in terms of dissociative-type mechanisms for both reactions, and comparisons were made with the related [Fe(CN)5L]n- system. © 1992. Fil:Olabe, J.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1992 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v11_n10_p1229_Chevalier http://hdl.handle.net/20.500.12110/paper_02775387_v11_n10_p1229_Chevalier
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Potassium pentacyanohydrazineruthenate(II) trihydrate has been synthesized and characterized by chemical methods, IR and electronic spectroscopy. The specific rate constants for the formation, kL, and dissociation, k-L, reactions of the [Ru(CN)5L]n- ions (L = N2H4, N2H5 +) were obtained, as well as the corresponding stability constants, KL. A value of pKa for the bonded N2H5 + species was also calculated. The results were interpreted in terms of dissociative-type mechanisms for both reactions, and comparisons were made with the related [Fe(CN)5L]n- system. © 1992.
author Olabe Iparraguirre, Jose Antonio
spellingShingle Olabe Iparraguirre, Jose Antonio
Preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(II) with hydrazine
author_facet Olabe Iparraguirre, Jose Antonio
author_sort Olabe Iparraguirre, Jose Antonio
title Preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(II) with hydrazine
title_short Preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(II) with hydrazine
title_full Preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(II) with hydrazine
title_fullStr Preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(II) with hydrazine
title_full_unstemmed Preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(II) with hydrazine
title_sort preparation, characterization and substitution kinetics in the complexes of pentacyanoruthenate(ii) with hydrazine
publishDate 1992
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02775387_v11_n10_p1229_Chevalier
http://hdl.handle.net/20.500.12110/paper_02775387_v11_n10_p1229_Chevalier
work_keys_str_mv AT olabeiparraguirrejoseantonio preparationcharacterizationandsubstitutionkineticsinthecomplexesofpentacyanoruthenateiiwithhydrazine
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