Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reacti...
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| Autores principales: | , , |
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| Publicado: |
2006
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v25_n16_p3799_Escola http://hdl.handle.net/20.500.12110/paper_02767333_v25_n16_p3799_Escola |
| Aporte de: |
| Sumario: | Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are very few examples of clean electrophilic addition of coordinated NO+ to alkenes. © 2006 American Chemical Society. |
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