Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes

Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reacti...

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Detalles Bibliográficos
Autores principales:	Escola, Natalia, Llebaria, Analuz, Doctorovich, Fabio Ariel
Publicado:	2006
Materias:	Chemical reactions Crystal structure Olefins X ray diffraction C-nitrosochloroalkanes Cyclooctene Electrophilic NOCl Potassium compounds
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v25_n16_p3799_Escola http://hdl.handle.net/20.500.12110/paper_02767333_v25_n16_p3799_Escola
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_02767333_v25_n16_p3799_Escola
record_format	dspace
spelling	paper:paper_02767333_v25_n16_p3799_Escola2023-06-08T15:25:55Z Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes Escola, Natalia Llebaria, Analuz Doctorovich, Fabio Ariel Chemical reactions Crystal structure Olefins X ray diffraction C-nitrosochloroalkanes Cyclooctene Electrophilic NOCl Potassium compounds Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are very few examples of clean electrophilic addition of coordinated NO+ to alkenes. © 2006 American Chemical Society. Fil:Escola, N. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Llebaría, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Doctorovich, F. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v25_n16_p3799_Escola http://hdl.handle.net/20.500.12110/paper_02767333_v25_n16_p3799_Escola
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Chemical reactions Crystal structure Olefins X ray diffraction C-nitrosochloroalkanes Cyclooctene Electrophilic NOCl Potassium compounds
spellingShingle	Chemical reactions Crystal structure Olefins X ray diffraction C-nitrosochloroalkanes Cyclooctene Electrophilic NOCl Potassium compounds Escola, Natalia Llebaria, Analuz Doctorovich, Fabio Ariel Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
topic_facet	Chemical reactions Crystal structure Olefins X ray diffraction C-nitrosochloroalkanes Cyclooctene Electrophilic NOCl Potassium compounds
description	Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCL4(CH3CN)(syn-I-chloro- 2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are very few examples of clean electrophilic addition of coordinated NO+ to alkenes. © 2006 American Chemical Society.
author	Escola, Natalia Llebaria, Analuz Doctorovich, Fabio Ariel
author_facet	Escola, Natalia Llebaria, Analuz Doctorovich, Fabio Ariel
author_sort	Escola, Natalia
title	Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_short	Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_full	Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_fullStr	Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_full_unstemmed	Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes
title_sort	formation of coordinated c-nitroso compounds by reaction of k[ircl 5no] with alkenes
publishDate	2006
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02767333_v25_n16_p3799_Escola http://hdl.handle.net/20.500.12110/paper_02767333_v25_n16_p3799_Escola
work_keys_str_mv	AT escolanatalia formationofcoordinatedcnitrosocompoundsbyreactionofkircl5nowithalkenes AT llebariaanaluz formationofcoordinatedcnitrosocompoundsbyreactionofkircl5nowithalkenes AT doctorovichfabioariel formationofcoordinatedcnitrosocompoundsbyreactionofkircl5nowithalkenes
_version_	1768543657030320128

Formation of coordinated C-nitroso compounds by reaction of K[IrCl 5NO] with alkenes

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