Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes

A model of an atmospheric pressure nitrogen glow discharge in high-gas temperature regimes is developed. The model considers a fairly complete set of chemical reactions, including several processes with the participation of electronically exited nitrogen atoms describing the energy balance and charg...

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Autor principal:	Kelly, Héctor Juan
Publicado:	2016
Materias:	Atmospheric pressure Electronic metastable atoms Glow discharge Nitrogen gas Atmospheric chemistry Atoms Charged particles Dissociation Glow discharges Ionization of gases Molecules Associative ionization Atomic collision Excited molecules Metastable atoms Nitrogen glow discharge Thermal dissociation Vibrationally excited Nitrogen
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02724324_v36_n4_p973_Prevosto http://hdl.handle.net/20.500.12110/paper_02724324_v36_n4_p973_Prevosto
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_02724324_v36_n4_p973_Prevosto
record_format	dspace
spelling	paper:paper_02724324_v36_n4_p973_Prevosto2023-06-08T15:25:02Z Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes Kelly, Héctor Juan Atmospheric pressure Electronic metastable atoms Glow discharge Nitrogen gas Atmospheric chemistry Atmospheric pressure Atoms Charged particles Dissociation Glow discharges Ionization of gases Molecules Associative ionization Atomic collision Excited molecules Metastable atoms Nitrogen gas Nitrogen glow discharge Thermal dissociation Vibrationally excited Nitrogen A model of an atmospheric pressure nitrogen glow discharge in high-gas temperature regimes is developed. The model considers a fairly complete set of chemical reactions, including several processes with the participation of electronically exited nitrogen atoms describing the energy balance and charged particles kinetic processes in the discharge. It is shown that the thermal dissociation of vibrationally excited molecules plays an essential role in the production of N(4S) atoms. The dominant ion within the investigated current range (52–187 mA) is the molecular N2 + with an increasing proportion of atomic N+ towards high-current values. The process of production of electrons within the almost whole current range is controlled predominantly by associative ionization in atomic collisions N(2P) + N(2P) → N2 + + e; being the N(2P) atoms mainly produced via quenching of N2(A3∑u +) electronically excited molecules by N(4S) atoms. The results of calculations are compared with the available experimental data and a good agreement is found. © 2016, Springer Science+Business Media New York. Fil:Kelly, H. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2016 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02724324_v36_n4_p973_Prevosto http://hdl.handle.net/20.500.12110/paper_02724324_v36_n4_p973_Prevosto
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Atmospheric pressure Electronic metastable atoms Glow discharge Nitrogen gas Atmospheric chemistry Atmospheric pressure Atoms Charged particles Dissociation Glow discharges Ionization of gases Molecules Associative ionization Atomic collision Excited molecules Metastable atoms Nitrogen gas Nitrogen glow discharge Thermal dissociation Vibrationally excited Nitrogen
spellingShingle	Atmospheric pressure Electronic metastable atoms Glow discharge Nitrogen gas Atmospheric chemistry Atmospheric pressure Atoms Charged particles Dissociation Glow discharges Ionization of gases Molecules Associative ionization Atomic collision Excited molecules Metastable atoms Nitrogen gas Nitrogen glow discharge Thermal dissociation Vibrationally excited Nitrogen Kelly, Héctor Juan Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes
topic_facet	Atmospheric pressure Electronic metastable atoms Glow discharge Nitrogen gas Atmospheric chemistry Atmospheric pressure Atoms Charged particles Dissociation Glow discharges Ionization of gases Molecules Associative ionization Atomic collision Excited molecules Metastable atoms Nitrogen gas Nitrogen glow discharge Thermal dissociation Vibrationally excited Nitrogen
description	A model of an atmospheric pressure nitrogen glow discharge in high-gas temperature regimes is developed. The model considers a fairly complete set of chemical reactions, including several processes with the participation of electronically exited nitrogen atoms describing the energy balance and charged particles kinetic processes in the discharge. It is shown that the thermal dissociation of vibrationally excited molecules plays an essential role in the production of N(4S) atoms. The dominant ion within the investigated current range (52–187 mA) is the molecular N2 + with an increasing proportion of atomic N+ towards high-current values. The process of production of electrons within the almost whole current range is controlled predominantly by associative ionization in atomic collisions N(2P) + N(2P) → N2 + + e; being the N(2P) atoms mainly produced via quenching of N2(A3∑u +) electronically excited molecules by N(4S) atoms. The results of calculations are compared with the available experimental data and a good agreement is found. © 2016, Springer Science+Business Media New York.
author	Kelly, Héctor Juan
author_facet	Kelly, Héctor Juan
author_sort	Kelly, Héctor Juan
title	Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes
title_short	Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes
title_full	Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes
title_fullStr	Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes
title_full_unstemmed	Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes
title_sort	modelling of an atmospheric pressure nitrogen glow discharge operating in high-gas temperature regimes
publishDate	2016
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02724324_v36_n4_p973_Prevosto http://hdl.handle.net/20.500.12110/paper_02724324_v36_n4_p973_Prevosto
work_keys_str_mv	AT kellyhectorjuan modellingofanatmosphericpressurenitrogenglowdischargeoperatinginhighgastemperatureregimes
_version_	1768542595125870592

Modelling of an Atmospheric Pressure Nitrogen Glow Discharge Operating in High-Gas Temperature Regimes

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