Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition

In this paper, we report a study of electrocatalytic oxidation of methanol on copper electrodes subjected to different surface treatments, either electrocorrosion or electrodeposition in the absence of strong hydrogen co-deposition. The surface morphology of treated electrodes was examined by Field...

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Autor principal:	Gonzalez, Graciela Alicia
Publicado:	2014
Materias:	Electrochemical properties Electrochemical techniques Microstructure Oxidation Surfaces Cyclic voltammetric techniques Effective surface area Electro-catalytic oxidation Field emission scanning electron microscopy Methanol concentration Oxidation of methanol Surface concentration Electrocatalysis Electrochemical oxidation Electrodeposition Electrodes Field emission microscopes Methanol
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v143_n3_p1012_Carugno http://hdl.handle.net/20.500.12110/paper_02540584_v143_n3_p1012_Carugno
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_02540584_v143_n3_p1012_Carugno
record_format	dspace
spelling	paper:paper_02540584_v143_n3_p1012_Carugno2023-06-08T15:21:56Z Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition Gonzalez, Graciela Alicia Electrochemical properties Electrochemical techniques Microstructure Oxidation Surfaces Cyclic voltammetric techniques Effective surface area Electro-catalytic oxidation Electrochemical techniques Field emission scanning electron microscopy Methanol concentration Oxidation of methanol Surface concentration Electrocatalysis Electrochemical oxidation Electrochemical properties Electrodeposition Electrodes Field emission microscopes Microstructure Oxidation Surfaces Methanol In this paper, we report a study of electrocatalytic oxidation of methanol on copper electrodes subjected to different surface treatments, either electrocorrosion or electrodeposition in the absence of strong hydrogen co-deposition. The surface morphology of treated electrodes was examined by Field Emission Scanning Electron Microscopy (FE-SEM). The effect of different treatment conditions and the methanol concentration dependence were evaluated by cyclic voltammetric technique. The results indicate that the oxidation of methanol can be enhanced by a suitable micro and nano structure generated by these treatments. This enhanced electrode activity is related to an increase of the effective surface area and/or to an increase of the surface concentration of electroactive molecules or intermediates. © 2013 Elsevier B.V. All rights reserved. Fil:González, G.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2014 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v143_n3_p1012_Carugno http://hdl.handle.net/20.500.12110/paper_02540584_v143_n3_p1012_Carugno
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Electrochemical properties Electrochemical techniques Microstructure Oxidation Surfaces Cyclic voltammetric techniques Effective surface area Electro-catalytic oxidation Electrochemical techniques Field emission scanning electron microscopy Methanol concentration Oxidation of methanol Surface concentration Electrocatalysis Electrochemical oxidation Electrochemical properties Electrodeposition Electrodes Field emission microscopes Microstructure Oxidation Surfaces Methanol
spellingShingle	Electrochemical properties Electrochemical techniques Microstructure Oxidation Surfaces Cyclic voltammetric techniques Effective surface area Electro-catalytic oxidation Electrochemical techniques Field emission scanning electron microscopy Methanol concentration Oxidation of methanol Surface concentration Electrocatalysis Electrochemical oxidation Electrochemical properties Electrodeposition Electrodes Field emission microscopes Microstructure Oxidation Surfaces Methanol Gonzalez, Graciela Alicia Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
topic_facet	Electrochemical properties Electrochemical techniques Microstructure Oxidation Surfaces Cyclic voltammetric techniques Effective surface area Electro-catalytic oxidation Electrochemical techniques Field emission scanning electron microscopy Methanol concentration Oxidation of methanol Surface concentration Electrocatalysis Electrochemical oxidation Electrochemical properties Electrodeposition Electrodes Field emission microscopes Microstructure Oxidation Surfaces Methanol
description	In this paper, we report a study of electrocatalytic oxidation of methanol on copper electrodes subjected to different surface treatments, either electrocorrosion or electrodeposition in the absence of strong hydrogen co-deposition. The surface morphology of treated electrodes was examined by Field Emission Scanning Electron Microscopy (FE-SEM). The effect of different treatment conditions and the methanol concentration dependence were evaluated by cyclic voltammetric technique. The results indicate that the oxidation of methanol can be enhanced by a suitable micro and nano structure generated by these treatments. This enhanced electrode activity is related to an increase of the effective surface area and/or to an increase of the surface concentration of electroactive molecules or intermediates. © 2013 Elsevier B.V. All rights reserved.
author	Gonzalez, Graciela Alicia
author_facet	Gonzalez, Graciela Alicia
author_sort	Gonzalez, Graciela Alicia
title	Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_short	Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_full	Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_fullStr	Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_full_unstemmed	Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
title_sort	enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition
publishDate	2014
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v143_n3_p1012_Carugno http://hdl.handle.net/20.500.12110/paper_02540584_v143_n3_p1012_Carugno
work_keys_str_mv	AT gonzalezgracielaalicia enhancedelectrochemicaloxidationofmethanoloncopperelectrodesmodifiedbyelectrocorrosionandelectrodeposition
_version_	1768546112518488064

Enhanced electrochemical oxidation of methanol on copper electrodes modified by electrocorrosion and electrodeposition

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