Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric

Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (663-963 °C) and temperature programme (t...

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Detalles Bibliográficos
Autores principales: Ramos, María Eva, Bonelli, Pablo R., Cukierman, Ana Lea
Publicado: 2009
Materias:
Adsorption
Microporous materials
Microstructure
Surface properties
Activated carbon cloth
Adsorption data
BET surface area
Breaking load
Dubinin-Radushkevich
Elemental compositions
Inert atmospheres
Mechanical strength
Micropore
Microporous
Modulus values
Nanofibre
Nitrogen isotherms
Phosphoric acid activation
Porosity development
Regenerated cellulose
Surface area
Temperature programme
Textural parameters
Thermal treatment
Thermal treatment temperature
Total pore volume
Treatment temperature
Atmospheric temperature
Carbon dioxide
Charcoal
Coal tar
Fabrics
Heat treatment
Isotherms
Mechanical properties
Microporosity
Nanofibers
Phosphoric acid
Trace analysis
Activated carbon
Carbon
Carbon Dioxide
Coal
Fabric
Heat Treatment
Mechanical Properties
Phosphoric Acid
Porous Materials
Surface Properties
Tar
Temperature
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v116_n2-3_p310_Ramos
http://hdl.handle.net/20.500.12110/paper_02540584_v116_n2-3_p310_Ramos
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paper:paper_02540584_v116_n2-3_p310_Ramos2023-06-08T15:21:55Z Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric Ramos, María Eva Bonelli, Pablo R. Cukierman, Ana Lea Adsorption Microporous materials Microstructure Surface properties Activated carbon cloth Adsorption data BET surface area Breaking load Dubinin-Radushkevich Elemental compositions Inert atmospheres Mechanical strength Micropore Microporous Modulus values Nanofibre Nitrogen isotherms Phosphoric acid activation Porosity development Regenerated cellulose Surface area Temperature programme Textural parameters Thermal treatment Thermal treatment temperature Total pore volume Treatment temperature Adsorption Atmospheric temperature Carbon dioxide Charcoal Coal tar Fabrics Heat treatment Isotherms Mechanical properties Microporosity Microporous materials Microstructure Nanofibers Phosphoric acid Surface properties Trace analysis Activated carbon Adsorption Carbon Carbon Dioxide Charcoal Coal Fabric Heat Treatment Isotherms Mechanical Properties Microstructure Phosphoric Acid Porous Materials Surface Properties Tar Temperature Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (663-963 °C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition, porosity development and mechanical strength of the resulting ACC were examined. Nitrogen isotherms at -196 °C, carbon dioxide isotherms at 0 °C, breaking loads and Youngs modulus values were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963 °C showed maximum BET surface area (1705 m2 g-1) and total pore volume (0.67 cm3 g-1). On the other hand the best mechanical strength was observed at 864 °C after a lower temperature isothermal step. Overall, the results indicated a stronger dependence of surface area, total pore volume, microporosity development and mechanical strength on the final treatment temperature than on the temperature programme. © 2009 Elsevier B.V. All rights reserved. Fil:Ramos, M.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bonelli, P.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cukierman, A.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2009 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v116_n2-3_p310_Ramos http://hdl.handle.net/20.500.12110/paper_02540584_v116_n2-3_p310_Ramos
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Adsorption
Microporous materials
Microstructure
Surface properties
Activated carbon cloth
Adsorption data
BET surface area
Breaking load
Dubinin-Radushkevich
Elemental compositions
Inert atmospheres
Mechanical strength
Micropore
Microporous
Modulus values
Nanofibre
Nitrogen isotherms
Phosphoric acid activation
Porosity development
Regenerated cellulose
Surface area
Temperature programme
Textural parameters
Thermal treatment
Thermal treatment temperature
Total pore volume
Treatment temperature
Adsorption
Atmospheric temperature
Carbon dioxide
Charcoal
Coal tar
Fabrics
Heat treatment
Isotherms
Mechanical properties
Microporosity
Microporous materials
Microstructure
Nanofibers
Phosphoric acid
Surface properties
Trace analysis
Activated carbon
Adsorption
Carbon
Carbon Dioxide
Charcoal
Coal
Fabric
Heat Treatment
Isotherms
Mechanical Properties
Microstructure
Phosphoric Acid
Porous Materials
Surface Properties
Tar
Temperature
spellingShingle Adsorption
Microporous materials
Microstructure
Surface properties
Activated carbon cloth
Adsorption data
BET surface area
Breaking load
Dubinin-Radushkevich
Elemental compositions
Inert atmospheres
Mechanical strength
Micropore
Microporous
Modulus values
Nanofibre
Nitrogen isotherms
Phosphoric acid activation
Porosity development
Regenerated cellulose
Surface area
Temperature programme
Textural parameters
Thermal treatment
Thermal treatment temperature
Total pore volume
Treatment temperature
Adsorption
Atmospheric temperature
Carbon dioxide
Charcoal
Coal tar
Fabrics
Heat treatment
Isotherms
Mechanical properties
Microporosity
Microporous materials
Microstructure
Nanofibers
Phosphoric acid
Surface properties
Trace analysis
Activated carbon
Adsorption
Carbon
Carbon Dioxide
Charcoal
Coal
Fabric
Heat Treatment
Isotherms
Mechanical Properties
Microstructure
Phosphoric Acid
Porous Materials
Surface Properties
Tar
Temperature
Ramos, María Eva
Bonelli, Pablo R.
Cukierman, Ana Lea
Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
topic_facet Adsorption
Microporous materials
Microstructure
Surface properties
Activated carbon cloth
Adsorption data
BET surface area
Breaking load
Dubinin-Radushkevich
Elemental compositions
Inert atmospheres
Mechanical strength
Micropore
Microporous
Modulus values
Nanofibre
Nitrogen isotherms
Phosphoric acid activation
Porosity development
Regenerated cellulose
Surface area
Temperature programme
Textural parameters
Thermal treatment
Thermal treatment temperature
Total pore volume
Treatment temperature
Adsorption
Atmospheric temperature
Carbon dioxide
Charcoal
Coal tar
Fabrics
Heat treatment
Isotherms
Mechanical properties
Microporosity
Microporous materials
Microstructure
Nanofibers
Phosphoric acid
Surface properties
Trace analysis
Activated carbon
Adsorption
Carbon
Carbon Dioxide
Charcoal
Coal
Fabric
Heat Treatment
Isotherms
Mechanical Properties
Microstructure
Phosphoric Acid
Porous Materials
Surface Properties
Tar
Temperature
description Activated carbon cloths (ACC) were prepared from Tencel®, a novel regenerated cellulose nanofibre fabric, by phosphoric acid activation in an inert atmosphere using different thermal treatment conditions. The effect of the final thermal treatment temperature (663-963 °C) and temperature programme (temperature of isothermal step and heating rate) on yield, elemental composition, porosity development and mechanical strength of the resulting ACC were examined. Nitrogen isotherms at -196 °C, carbon dioxide isotherms at 0 °C, breaking loads and Youngs modulus values were determined for all the samples. Adsorption data were fitted to different models (BET, Dubinin-Radushkevich, αS) to evaluate textural parameters of the ACC. The samples were essentially microporous and presented good physical appearance. Higher treatment temperatures resulted in higher BET surface areas and total pore volumes, also leading to larger micropore widths. The ACC prepared at 963 °C showed maximum BET surface area (1705 m2 g-1) and total pore volume (0.67 cm3 g-1). On the other hand the best mechanical strength was observed at 864 °C after a lower temperature isothermal step. Overall, the results indicated a stronger dependence of surface area, total pore volume, microporosity development and mechanical strength on the final treatment temperature than on the temperature programme. © 2009 Elsevier B.V. All rights reserved.
author Ramos, María Eva
Bonelli, Pablo R.
Cukierman, Ana Lea
author_facet Ramos, María Eva
Bonelli, Pablo R.
Cukierman, Ana Lea
author_sort Ramos, María Eva
title Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_short Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_full Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_fullStr Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_full_unstemmed Influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
title_sort influence of thermal treatment conditions on porosity development and mechanical properties of activated carbon cloths from a novel nanofibre-made fabric
publishDate 2009
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_02540584_v116_n2-3_p310_Ramos
http://hdl.handle.net/20.500.12110/paper_02540584_v116_n2-3_p310_Ramos
work_keys_str_mv AT ramosmariaeva influenceofthermaltreatmentconditionsonporositydevelopmentandmechanicalpropertiesofactivatedcarbonclothsfromanovelnanofibremadefabric
AT bonellipablor influenceofthermaltreatmentconditionsonporositydevelopmentandmechanicalpropertiesofactivatedcarbonclothsfromanovelnanofibremadefabric
AT cukiermananalea influenceofthermaltreatmentconditionsonporositydevelopmentandmechanicalpropertiesofactivatedcarbonclothsfromanovelnanofibremadefabric
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