Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii

Seven new withanolides, salpichrolides O-U (1-7), the known 2,3-dihydrosalpichrolide B (9), a substance not previously isolated from a natural source, and three known compounds, salpichrolide D (8), salpichrolide A (10), and salpichrolide C (11), were isolated and characterized from the aerial parts...

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Publicado: 2013
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oat
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01633864_v76_n12_p2219_Nicotra
http://hdl.handle.net/20.500.12110/paper_01633864_v76_n12_p2219_Nicotra
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spelling paper:paper_01633864_v76_n12_p2219_Nicotra2023-06-08T15:14:19Z Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii 2,3 dihydrosalpichrolide b salpichrolide a salpichrolide c salpichrolide o salpichrolide p salpichrolide q salpichrolide r salpichrolide s salpichrolide t salpichrolide u unclassified drug withanolide article lettuce mass spectrometry nuclear magnetic resonance spectroscopy oat phytotoxicity plant Salpichroa origanifolia Salpichroa tristis var. lehmannii Argentina Ergosterol Molecular Structure Solanaceae Withanolides Seven new withanolides, salpichrolides O-U (1-7), the known 2,3-dihydrosalpichrolide B (9), a substance not previously isolated from a natural source, and three known compounds, salpichrolide D (8), salpichrolide A (10), and salpichrolide C (11), were isolated and characterized from the aerial parts of Salpichroa origanifolia and S. tristis var. lehmannii. Compounds 1-4 and 8 have an oxygenated D ring, while compounds 5-7 and 9-11 possess a six-membered aromatic D ring. The structures of the isolated compounds were identified by analysis of their spectroscopic data including NMR and MS. Withanolides 1, 3, 8, 10, and 11 exhibited selective radicle growth inhibition toward Lactuca sativa (lettuce) at 150 and 400 ppm. © 2013 The American Chemical Society and American Society of Pharmacognosy. 2013 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01633864_v76_n12_p2219_Nicotra http://hdl.handle.net/20.500.12110/paper_01633864_v76_n12_p2219_Nicotra
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic 2,3 dihydrosalpichrolide b
salpichrolide a
salpichrolide c
salpichrolide o
salpichrolide p
salpichrolide q
salpichrolide r
salpichrolide s
salpichrolide t
salpichrolide u
unclassified drug
withanolide
article
lettuce
mass spectrometry
nuclear magnetic resonance spectroscopy
oat
phytotoxicity
plant
Salpichroa origanifolia
Salpichroa tristis var. lehmannii
Argentina
Ergosterol
Molecular Structure
Solanaceae
Withanolides
spellingShingle 2,3 dihydrosalpichrolide b
salpichrolide a
salpichrolide c
salpichrolide o
salpichrolide p
salpichrolide q
salpichrolide r
salpichrolide s
salpichrolide t
salpichrolide u
unclassified drug
withanolide
article
lettuce
mass spectrometry
nuclear magnetic resonance spectroscopy
oat
phytotoxicity
plant
Salpichroa origanifolia
Salpichroa tristis var. lehmannii
Argentina
Ergosterol
Molecular Structure
Solanaceae
Withanolides
Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii
topic_facet 2,3 dihydrosalpichrolide b
salpichrolide a
salpichrolide c
salpichrolide o
salpichrolide p
salpichrolide q
salpichrolide r
salpichrolide s
salpichrolide t
salpichrolide u
unclassified drug
withanolide
article
lettuce
mass spectrometry
nuclear magnetic resonance spectroscopy
oat
phytotoxicity
plant
Salpichroa origanifolia
Salpichroa tristis var. lehmannii
Argentina
Ergosterol
Molecular Structure
Solanaceae
Withanolides
description Seven new withanolides, salpichrolides O-U (1-7), the known 2,3-dihydrosalpichrolide B (9), a substance not previously isolated from a natural source, and three known compounds, salpichrolide D (8), salpichrolide A (10), and salpichrolide C (11), were isolated and characterized from the aerial parts of Salpichroa origanifolia and S. tristis var. lehmannii. Compounds 1-4 and 8 have an oxygenated D ring, while compounds 5-7 and 9-11 possess a six-membered aromatic D ring. The structures of the isolated compounds were identified by analysis of their spectroscopic data including NMR and MS. Withanolides 1, 3, 8, 10, and 11 exhibited selective radicle growth inhibition toward Lactuca sativa (lettuce) at 150 and 400 ppm. © 2013 The American Chemical Society and American Society of Pharmacognosy.
title Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii
title_short Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii
title_full Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii
title_fullStr Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii
title_full_unstemmed Withanolides with phytotoxic activity from two species of the genus salpichroa: S. origanifolia and s. tristis var. lehmannii
title_sort withanolides with phytotoxic activity from two species of the genus salpichroa: s. origanifolia and s. tristis var. lehmannii
publishDate 2013
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01633864_v76_n12_p2219_Nicotra
http://hdl.handle.net/20.500.12110/paper_01633864_v76_n12_p2219_Nicotra
_version_ 1768546578918801408