Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent
Biodegradable and non-retrogradable starch-glycerol based films were obtained using citric acid (CA) as crosslinking agent at 75 °C. This material allowed decreasing water vapor permeability (WVP) more than 35%, remained amorphous for at least 45 days as a result of the network formed by the CA that...
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01448617_v138_n_p66_Seligra http://hdl.handle.net/20.500.12110/paper_01448617_v138_n_p66_Seligra |
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paper:paper_01448617_v138_n_p66_Seligra2023-06-08T15:12:01Z Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent Famá, Lucía Mercedes Goyanes, Silvia Nair Biodegradability Biodegradable edible films Citric acid Crosslinking Starch Amorphous films Biodegradability Biodegradation Citric acid Composting Differential thermal analysis Gelation Glycerol Starch Thermoanalysis Cross linking agents Degradability Edible films Process temperature Starch retrogradation Swelling process Water vapor permeability Crosslinking citric acid cross linking reagent dimethyl sulfoxide glycerol starch water bioremediation chemistry infrared spectroscopy microbiology permeability temperature thermogravimetry Biodegradation, Environmental Citric Acid Cross-Linking Reagents Dimethyl Sulfoxide Glycerol Permeability Soil Microbiology Spectroscopy, Fourier Transform Infrared Starch Temperature Thermogravimetry Water Biodegradable and non-retrogradable starch-glycerol based films were obtained using citric acid (CA) as crosslinking agent at 75 °C. This material allowed decreasing water vapor permeability (WVP) more than 35%, remained amorphous for at least 45 days as a result of the network formed by the CA that avoided starch retrogradation and maintained the degradability in compost, occurring only six days after the films without citric acid. A simulation of the gelatinization process of starch-glycerol with and without CA, using a differential thermal analysis device, showed that the system with CA completed the gelatinization 5 °C before than the other and, CA first reacted with glycerol and then starch-glycerol-CA reaction occurred. The temperature at which the gelatinization process was carried out was critical to obtain the best results. An increase of gelatinization process temperature at 85 °C in system with CA, led to a worsening on WVP and its integrity after a swelling process with dimethylsulphoxide (DMSO), compared to the films processed at 75 °C. © 2015 Elsevier Ltd. Fil:Famá, L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Goyanes, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2016 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01448617_v138_n_p66_Seligra http://hdl.handle.net/20.500.12110/paper_01448617_v138_n_p66_Seligra |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Biodegradability Biodegradable edible films Citric acid Crosslinking Starch Amorphous films Biodegradability Biodegradation Citric acid Composting Differential thermal analysis Gelation Glycerol Starch Thermoanalysis Cross linking agents Degradability Edible films Process temperature Starch retrogradation Swelling process Water vapor permeability Crosslinking citric acid cross linking reagent dimethyl sulfoxide glycerol starch water bioremediation chemistry infrared spectroscopy microbiology permeability temperature thermogravimetry Biodegradation, Environmental Citric Acid Cross-Linking Reagents Dimethyl Sulfoxide Glycerol Permeability Soil Microbiology Spectroscopy, Fourier Transform Infrared Starch Temperature Thermogravimetry Water |
spellingShingle |
Biodegradability Biodegradable edible films Citric acid Crosslinking Starch Amorphous films Biodegradability Biodegradation Citric acid Composting Differential thermal analysis Gelation Glycerol Starch Thermoanalysis Cross linking agents Degradability Edible films Process temperature Starch retrogradation Swelling process Water vapor permeability Crosslinking citric acid cross linking reagent dimethyl sulfoxide glycerol starch water bioremediation chemistry infrared spectroscopy microbiology permeability temperature thermogravimetry Biodegradation, Environmental Citric Acid Cross-Linking Reagents Dimethyl Sulfoxide Glycerol Permeability Soil Microbiology Spectroscopy, Fourier Transform Infrared Starch Temperature Thermogravimetry Water Famá, Lucía Mercedes Goyanes, Silvia Nair Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent |
topic_facet |
Biodegradability Biodegradable edible films Citric acid Crosslinking Starch Amorphous films Biodegradability Biodegradation Citric acid Composting Differential thermal analysis Gelation Glycerol Starch Thermoanalysis Cross linking agents Degradability Edible films Process temperature Starch retrogradation Swelling process Water vapor permeability Crosslinking citric acid cross linking reagent dimethyl sulfoxide glycerol starch water bioremediation chemistry infrared spectroscopy microbiology permeability temperature thermogravimetry Biodegradation, Environmental Citric Acid Cross-Linking Reagents Dimethyl Sulfoxide Glycerol Permeability Soil Microbiology Spectroscopy, Fourier Transform Infrared Starch Temperature Thermogravimetry Water |
description |
Biodegradable and non-retrogradable starch-glycerol based films were obtained using citric acid (CA) as crosslinking agent at 75 °C. This material allowed decreasing water vapor permeability (WVP) more than 35%, remained amorphous for at least 45 days as a result of the network formed by the CA that avoided starch retrogradation and maintained the degradability in compost, occurring only six days after the films without citric acid. A simulation of the gelatinization process of starch-glycerol with and without CA, using a differential thermal analysis device, showed that the system with CA completed the gelatinization 5 °C before than the other and, CA first reacted with glycerol and then starch-glycerol-CA reaction occurred. The temperature at which the gelatinization process was carried out was critical to obtain the best results. An increase of gelatinization process temperature at 85 °C in system with CA, led to a worsening on WVP and its integrity after a swelling process with dimethylsulphoxide (DMSO), compared to the films processed at 75 °C. © 2015 Elsevier Ltd. |
author |
Famá, Lucía Mercedes Goyanes, Silvia Nair |
author_facet |
Famá, Lucía Mercedes Goyanes, Silvia Nair |
author_sort |
Famá, Lucía Mercedes |
title |
Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent |
title_short |
Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent |
title_full |
Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent |
title_fullStr |
Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent |
title_full_unstemmed |
Biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent |
title_sort |
biodegradable and non-retrogradable eco-films based on starch-glycerol with citric acid as crosslinking agent |
publishDate |
2016 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01448617_v138_n_p66_Seligra http://hdl.handle.net/20.500.12110/paper_01448617_v138_n_p66_Seligra |
work_keys_str_mv |
AT famaluciamercedes biodegradableandnonretrogradableecofilmsbasedonstarchglycerolwithcitricacidascrosslinkingagent AT goyanessilvianair biodegradableandnonretrogradableecofilmsbasedonstarchglycerolwithcitricacidascrosslinkingagent |
_version_ |
1768544173402619904 |