Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate
The title copper complex, [Cu(H2P2O 7)(C15H11N3)]2·4. 5H2O, consists of two very similar independent Cu(Tpy)H 2P2O7 monomeric units (Tpy is 2,2′:6′,2″-terpyridine) plus four and a half water mol-ecules of hydration, some of which are disordered. Tpy units bind through the usual triple bite via their...
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2011
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v67_n5_pm140_Perec http://hdl.handle.net/20.500.12110/paper_01082701_v67_n5_pm140_Perec |
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paper:paper_01082701_v67_n5_pm140_Perec2023-06-08T15:10:43Z Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate Perec, Mireille Apical positions Complex molecules Copper (ii) Copper complexes Dihydrogen Dinuclear units Monomeric units Phosphate group Square pyramid Terpyridines Atoms Chromophores Complexation Hydrates Hydration Hydrogen Hydrogen bonds Copper compounds bis((dihydrogen pyrophosphato kappa(2)O,O')(2,2':6',2'' terpyridine kappa(3)N,N',N'')copper(II)) 4.5 hydrate bis((dihydrogen pyrophosphato-kappa(2)O,O')(2,2':6',2''-terpyridine-kappa(3)N,N',N'')copper(II)) 4.5-hydrate bis(dihydroxyethyldithiocarbamate)Cu (II) complex copper diethyldithiocarbamic acid drug derivative ion organometallic compound pyridine derivative article chemical structure chemistry dimerization hydrogen bond X ray crystallography Copper Crystallography, X-Ray Dimerization Ditiocarb Hydrogen Bonding Ions Molecular Structure Organometallic Compounds Pyridines The title copper complex, [Cu(H2P2O 7)(C15H11N3)]2·4. 5H2O, consists of two very similar independent Cu(Tpy)H 2P2O7 monomeric units (Tpy is 2,2′:6′,2″-terpyridine) plus four and a half water mol-ecules of hydration, some of which are disordered. Tpy units bind through the usual triple bite via their N atoms, and the H2P2O7 2- anions coordinate through two O atoms from two different phosphate units. Each independent CuN3O2 chromophore can be described as a slightly deformed square pyramid, with one of them having a sixth, semicoordinated, O atom from a centrosymmetrically related CuN 3O2 unit in a weakly bound second apical position suggesting an octa-hedral environment for the cation and weak dimerization of the molecule. The two independent complex molecules are connected via two strong O - H⋯O inter-actions between the phosphate groups to form hydrogen-bonded dinuclear units, further linked into [111] columns, resulting in a very complex three-dimensional supra-molecular structure through a variety of classical and nonclassical hydrogen bonds, as well as π-π interactions. © 2011 International Union of Crystallography. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2011 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v67_n5_pm140_Perec http://hdl.handle.net/20.500.12110/paper_01082701_v67_n5_pm140_Perec |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Apical positions Complex molecules Copper (ii) Copper complexes Dihydrogen Dinuclear units Monomeric units Phosphate group Square pyramid Terpyridines Atoms Chromophores Complexation Hydrates Hydration Hydrogen Hydrogen bonds Copper compounds bis((dihydrogen pyrophosphato kappa(2)O,O')(2,2':6',2'' terpyridine kappa(3)N,N',N'')copper(II)) 4.5 hydrate bis((dihydrogen pyrophosphato-kappa(2)O,O')(2,2':6',2''-terpyridine-kappa(3)N,N',N'')copper(II)) 4.5-hydrate bis(dihydroxyethyldithiocarbamate)Cu (II) complex copper diethyldithiocarbamic acid drug derivative ion organometallic compound pyridine derivative article chemical structure chemistry dimerization hydrogen bond X ray crystallography Copper Crystallography, X-Ray Dimerization Ditiocarb Hydrogen Bonding Ions Molecular Structure Organometallic Compounds Pyridines |
| spellingShingle |
Apical positions Complex molecules Copper (ii) Copper complexes Dihydrogen Dinuclear units Monomeric units Phosphate group Square pyramid Terpyridines Atoms Chromophores Complexation Hydrates Hydration Hydrogen Hydrogen bonds Copper compounds bis((dihydrogen pyrophosphato kappa(2)O,O')(2,2':6',2'' terpyridine kappa(3)N,N',N'')copper(II)) 4.5 hydrate bis((dihydrogen pyrophosphato-kappa(2)O,O')(2,2':6',2''-terpyridine-kappa(3)N,N',N'')copper(II)) 4.5-hydrate bis(dihydroxyethyldithiocarbamate)Cu (II) complex copper diethyldithiocarbamic acid drug derivative ion organometallic compound pyridine derivative article chemical structure chemistry dimerization hydrogen bond X ray crystallography Copper Crystallography, X-Ray Dimerization Ditiocarb Hydrogen Bonding Ions Molecular Structure Organometallic Compounds Pyridines Perec, Mireille Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate |
| topic_facet |
Apical positions Complex molecules Copper (ii) Copper complexes Dihydrogen Dinuclear units Monomeric units Phosphate group Square pyramid Terpyridines Atoms Chromophores Complexation Hydrates Hydration Hydrogen Hydrogen bonds Copper compounds bis((dihydrogen pyrophosphato kappa(2)O,O')(2,2':6',2'' terpyridine kappa(3)N,N',N'')copper(II)) 4.5 hydrate bis((dihydrogen pyrophosphato-kappa(2)O,O')(2,2':6',2''-terpyridine-kappa(3)N,N',N'')copper(II)) 4.5-hydrate bis(dihydroxyethyldithiocarbamate)Cu (II) complex copper diethyldithiocarbamic acid drug derivative ion organometallic compound pyridine derivative article chemical structure chemistry dimerization hydrogen bond X ray crystallography Copper Crystallography, X-Ray Dimerization Ditiocarb Hydrogen Bonding Ions Molecular Structure Organometallic Compounds Pyridines |
| description |
The title copper complex, [Cu(H2P2O 7)(C15H11N3)]2·4. 5H2O, consists of two very similar independent Cu(Tpy)H 2P2O7 monomeric units (Tpy is 2,2′:6′,2″-terpyridine) plus four and a half water mol-ecules of hydration, some of which are disordered. Tpy units bind through the usual triple bite via their N atoms, and the H2P2O7 2- anions coordinate through two O atoms from two different phosphate units. Each independent CuN3O2 chromophore can be described as a slightly deformed square pyramid, with one of them having a sixth, semicoordinated, O atom from a centrosymmetrically related CuN 3O2 unit in a weakly bound second apical position suggesting an octa-hedral environment for the cation and weak dimerization of the molecule. The two independent complex molecules are connected via two strong O - H⋯O inter-actions between the phosphate groups to form hydrogen-bonded dinuclear units, further linked into [111] columns, resulting in a very complex three-dimensional supra-molecular structure through a variety of classical and nonclassical hydrogen bonds, as well as π-π interactions. © 2011 International Union of Crystallography. |
| author |
Perec, Mireille |
| author_facet |
Perec, Mireille |
| author_sort |
Perec, Mireille |
| title |
Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate |
| title_short |
Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate |
| title_full |
Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate |
| title_fullStr |
Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate |
| title_full_unstemmed |
Bis[(dihydrogen pyrophosphatoκ-2 O,O′)(2,2′: 6′,2″-terpyridine-κ3 N,N′,N″)copper(II) ] 4.5-hydrate |
| title_sort |
bis[(dihydrogen pyrophosphatoκ-2 o,o′)(2,2′: 6′,2″-terpyridine-κ3 n,n′,n″)copper(ii) ] 4.5-hydrate |
| publishDate |
2011 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v67_n5_pm140_Perec http://hdl.handle.net/20.500.12110/paper_01082701_v67_n5_pm140_Perec |
| work_keys_str_mv |
AT perecmireille bisdihydrogenpyrophosphatok2oo2262terpyridinek3nnncopperii45hydrate |
| _version_ |
1768546577853448192 |