4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases
The crystal structure of the dimeric title compound, C19H 22O5H, is dominated by a head-to-head hydrogen-bonding inter-action between centrosymmetrically related carboxyl groups in each monomer. The result is a dimeric axis of unusual length (ca 34 Å), but still shorter than what could be expected f...
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v65_n3_po81_Montani http://hdl.handle.net/20.500.12110/paper_01082701_v65_n3_po81_Montani |
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paper:paper_01082701_v65_n3_po81_Montani2023-06-08T15:10:42Z 4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases Cukiernik, Fabio Daniel Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure The crystal structure of the dimeric title compound, C19H 22O5H, is dominated by a head-to-head hydrogen-bonding inter-action between centrosymmetrically related carboxyl groups in each monomer. The result is a dimeric axis of unusual length (ca 34 Å), but still shorter than what could be expected for a fully extended chain, owing to two turning points in the oligo-eth-oxy ends. This allows for an explanation of the structure of the smectic mesophase exhibited by this compound and at the same time fully validates former geometric estimations based on PM3 calculations. © 2009 International Union of Crystallography. Fil:Cukiernik, F.D. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2009 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v65_n3_po81_Montani http://hdl.handle.net/20.500.12110/paper_01082701_v65_n3_po81_Montani |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure |
spellingShingle |
Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure Cukiernik, Fabio Daniel 4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases |
topic_facet |
Carboxylic acids Hydrogen Organic acids Carboxyl groups Hydrogen bondings Pm3 calculations Smectic mesophase Smectic phasis Title compounds Turning points Crystal structure |
description |
The crystal structure of the dimeric title compound, C19H 22O5H, is dominated by a head-to-head hydrogen-bonding inter-action between centrosymmetrically related carboxyl groups in each monomer. The result is a dimeric axis of unusual length (ca 34 Å), but still shorter than what could be expected for a fully extended chain, owing to two turning points in the oligo-eth-oxy ends. This allows for an explanation of the structure of the smectic mesophase exhibited by this compound and at the same time fully validates former geometric estimations based on PM3 calculations. © 2009 International Union of Crystallography. |
author |
Cukiernik, Fabio Daniel |
author_facet |
Cukiernik, Fabio Daniel |
author_sort |
Cukiernik, Fabio Daniel |
title |
4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases |
title_short |
4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases |
title_full |
4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases |
title_fullStr |
4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases |
title_full_unstemmed |
4'-[2-(2-Ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: Correlation between its crystalline and smectic phases |
title_sort |
4'-[2-(2-ethoxy-ethoxy)eth-oxy]-bi-phenyl-4-carboxylic acid: correlation between its crystalline and smectic phases |
publishDate |
2009 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v65_n3_po81_Montani http://hdl.handle.net/20.500.12110/paper_01082701_v65_n3_po81_Montani |
work_keys_str_mv |
AT cukiernikfabiodaniel 422ethoxyethoxyethoxybiphenyl4carboxylicacidcorrelationbetweenitscrystallineandsmecticphases |
_version_ |
1768545640743174144 |