A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)

The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and t...

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Detalles Bibliográficos
Publicado: 2002
Materias:
Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v58_n4_pm235_Albores
http://hdl.handle.net/20.500.12110/paper_01082701_v58_n4_pm235_Albores
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
Descripción
Sumario:The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state.

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