A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)

The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and t...

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Detalles Bibliográficos
Publicado: 2002
Materias:
Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v58_n4_pm235_Albores
http://hdl.handle.net/20.500.12110/paper_01082701_v58_n4_pm235_Albores
Aporte de:
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_01082701_v58_n4_pm235_Albores
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spelling paper:paper_01082701_v58_n4_pm235_Albores2023-06-08T15:10:40Z A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II) Chemical bonds Complexation Crystallization Ruthenium compounds Solutions Stereochemistry Synthesis (chemical) Hybridization Ligands Crystal structure The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state. 2002 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v58_n4_pm235_Albores http://hdl.handle.net/20.500.12110/paper_01082701_v58_n4_pm235_Albores
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
spellingShingle Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
topic_facet Chemical bonds
Complexation
Crystallization
Ruthenium compounds
Solutions
Stereochemistry
Synthesis (chemical)
Hybridization
Ligands
Crystal structure
description The octahedral title compound, [Ru(C2H5O)(NO)(NO2)2-(C6H 16N2)], crystallizes in the rhombohedral space group P31 with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state.
title A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_short A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_full A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_fullStr A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_full_unstemmed A complex containing three different kinds of Ru-N bonds: Ethoxydinitro-nitrosyl(N, N, N′, N′-tetramethylethylenediamine-κ 2N, N′)ruthenium(II)
title_sort complex containing three different kinds of ru-n bonds: ethoxydinitro-nitrosyl(n, n, n′, n′-tetramethylethylenediamine-κ 2n, n′)ruthenium(ii)
publishDate 2002
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v58_n4_pm235_Albores
http://hdl.handle.net/20.500.12110/paper_01082701_v58_n4_pm235_Albores
_version_ 1768541602540683264

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