The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]

The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordinat...

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Detalles Bibliográficos
Autores principales: Baggio, Ricardo F., Perec, Mireille
Publicado: 1996
Materias:
Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v52_n4_p823_Baggio
http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_01082701_v52_n4_p823_Baggio
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spelling paper:paper_01082701_v52_n4_p823_Baggio2023-06-08T15:10:37Z The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br] Baggio, Ricardo F. Perec, Mireille Bromine compounds Cadmium compounds Chlorine compounds Crystal atomic structure Molecular structure Spectroscopic analysis Cadmium halide bis(diethyldithiocarbamate) complexes Isomorphous compounds Mononuclear complexes Organometallics The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively. Fil:Baggio, R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Perec, M. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1996 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v52_n4_p823_Baggio http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
spellingShingle Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
Baggio, Ricardo F.
Perec, Mireille
The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
topic_facet Bromine compounds
Cadmium compounds
Chlorine compounds
Crystal atomic structure
Molecular structure
Spectroscopic analysis
Cadmium halide bis(diethyldithiocarbamate) complexes
Isomorphous compounds
Mononuclear complexes
Organometallics
description The title compounds, tetraphenylphosphonium chlorobis(diethyldithiocarbamato-S,S)cadmium(II), (C24H20P)-[CdCl(C5H10NS 2)2], (1), and tetraphenylphosphonium bromobis(diethyldithiocarbamato-S,S)cadmium(II), (C24-H20P)[CdBr(C5H10NS 2)2], (2), are isomorphous. The compexes are mononuclear with coordination spheres of the types S4Cl and S4Br, respectively. The central Cd atom is linked to four S atoms and two bidentate dithiocarbamate ligands and to the halide atom. The resulting Cd-atom coordination geometry is halfway between trigonal bipyrimidal and square pyramidal. Principal dimensions include: Cd-S 2.573 (1)-2.682 (1) in (1) and 2.571 (3)-2.736 (2) Å in (2); Cd-Cl and Cd-Br 2.462 (1) and 2.626 (1) Å, respectively.
author Baggio, Ricardo F.
Perec, Mireille
author_facet Baggio, Ricardo F.
Perec, Mireille
author_sort Baggio, Ricardo F.
title The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_short The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_full The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_fullStr The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_full_unstemmed The five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [PPh4][Cd(S2CNEt2)2Cl] and [PPh4][Cd(S2CNEt2)2Br]
title_sort five-coordinate cadmium halide bis(diethyldithiocarbamate) complexes [pph4][cd(s2cnet2)2cl] and [pph4][cd(s2cnet2)2br]
publishDate 1996
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_01082701_v52_n4_p823_Baggio
http://hdl.handle.net/20.500.12110/paper_01082701_v52_n4_p823_Baggio
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