Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide

The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isop...

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Autor principal: Braslavsky, Silvia Elsa
Publicado: 1967
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00456470_v_n_p414_Braslavsky
http://hdl.handle.net/20.500.12110/paper_00456470_v_n_p414_Braslavsky
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
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spelling paper:paper_00456470_v_n_p414_Braslavsky2023-06-08T15:05:14Z Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide Braslavsky, Silvia Elsa The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isopropyl radicals, in agreement with values given in the literature. This shows that alkyl iodides can be a useful source of free radicals. Fil:Braslavsky, S.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1967 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00456470_v_n_p414_Braslavsky http://hdl.handle.net/20.500.12110/paper_00456470_v_n_p414_Braslavsky
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The gas-phase photolysis of isopropyl iodide with light of wavelengths ≥3130 Å has been reinvestigated. In presence of mercury the only source of propene is the disproportionation of the isopropyl radicals. A value of 0·58 ± 0·04 was obtained for the combination- disproportionation ratio of the isopropyl radicals, in agreement with values given in the literature. This shows that alkyl iodides can be a useful source of free radicals.
author Braslavsky, Silvia Elsa
spellingShingle Braslavsky, Silvia Elsa
Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide
author_facet Braslavsky, Silvia Elsa
author_sort Braslavsky, Silvia Elsa
title Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide
title_short Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide
title_full Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide
title_fullStr Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide
title_full_unstemmed Alkyl iodides as a source of alkyl radicals. Part I. Mechanism of the gas-phase photolysis of isopropyl iodide
title_sort alkyl iodides as a source of alkyl radicals. part i. mechanism of the gas-phase photolysis of isopropyl iodide
publishDate 1967
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00456470_v_n_p414_Braslavsky
http://hdl.handle.net/20.500.12110/paper_00456470_v_n_p414_Braslavsky
work_keys_str_mv AT braslavskysilviaelsa alkyliodidesasasourceofalkylradicalspartimechanismofthegasphasephotolysisofisopropyliodide
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