Novel thiol-derivatized zinc(II) phthalocyanines

Preparation and characterization of tetrasubstituted zinc(II) phthalocyanines in which sulfur is not linked to the macrocycle are reported herein for the first time. Thioacetic acid S-[3-(3,4-dicyano-phenoxy)-propyl]ester (4) was synthesized in 55% yield from 4-nitrophthalonitrile and thioacetic aci...

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Autor principal:	Dicelio, Lelia Elina
Publicado:	2009
Materias:	Spectroscopy Synthesis Thiol-phthalocyanines (3 hydroxypropyl)ester 1,8 diazabicyclo[5.4.0]undec 7 ene 3 (3,4 dicyano phenoxy) propyl ester 4 nitrophthalonitrile alkene derivative butanol macrocyclic compound methoxide sodium nitrile phthalocyanine phthalocyanine zinc phthalonitrile sodium derivative sulfur thioacetic acid thiol derivative unclassified drug zinc acetate absorption spectrophotometry article chemical structure controlled study spectrofluorometry substitution reaction synthesis
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v50_n21_p2467_GarciaVior http://hdl.handle.net/20.500.12110/paper_00404039_v50_n21_p2467_GarciaVior
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00404039_v50_n21_p2467_GarciaVior
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spelling	paper:paper_00404039_v50_n21_p2467_GarciaVior2023-06-08T15:04:28Z Novel thiol-derivatized zinc(II) phthalocyanines Dicelio, Lelia Elina Spectroscopy Synthesis Thiol-phthalocyanines (3 hydroxypropyl)ester 1,8 diazabicyclo[5.4.0]undec 7 ene 3 (3,4 dicyano phenoxy) propyl ester 4 nitrophthalonitrile alkene derivative butanol macrocyclic compound methoxide sodium nitrile phthalocyanine phthalocyanine zinc phthalonitrile sodium derivative sulfur thioacetic acid thiol derivative unclassified drug zinc acetate absorption spectrophotometry article chemical structure controlled study spectrofluorometry substitution reaction synthesis Preparation and characterization of tetrasubstituted zinc(II) phthalocyanines in which sulfur is not linked to the macrocycle are reported herein for the first time. Thioacetic acid S-[3-(3,4-dicyano-phenoxy)-propyl]ester (4) was synthesized in 55% yield from 4-nitrophthalonitrile and thioacetic acid S-(3-hydroxy-propyl)ester (3). Tetrasusbtituted thiol-derivatized zinc(II) phthalocyanine 5 was obtained from 4 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene in butanol. Treatment of 5 with sodium methoxide afforded phthalocyanine 6. © 2009 Elsevier Ltd. All rights reserved. Fil:Dicelio, L.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2009 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v50_n21_p2467_GarciaVior http://hdl.handle.net/20.500.12110/paper_00404039_v50_n21_p2467_GarciaVior
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Spectroscopy Synthesis Thiol-phthalocyanines (3 hydroxypropyl)ester 1,8 diazabicyclo[5.4.0]undec 7 ene 3 (3,4 dicyano phenoxy) propyl ester 4 nitrophthalonitrile alkene derivative butanol macrocyclic compound methoxide sodium nitrile phthalocyanine phthalocyanine zinc phthalonitrile sodium derivative sulfur thioacetic acid thiol derivative unclassified drug zinc acetate absorption spectrophotometry article chemical structure controlled study spectrofluorometry substitution reaction synthesis
spellingShingle	Spectroscopy Synthesis Thiol-phthalocyanines (3 hydroxypropyl)ester 1,8 diazabicyclo[5.4.0]undec 7 ene 3 (3,4 dicyano phenoxy) propyl ester 4 nitrophthalonitrile alkene derivative butanol macrocyclic compound methoxide sodium nitrile phthalocyanine phthalocyanine zinc phthalonitrile sodium derivative sulfur thioacetic acid thiol derivative unclassified drug zinc acetate absorption spectrophotometry article chemical structure controlled study spectrofluorometry substitution reaction synthesis Dicelio, Lelia Elina Novel thiol-derivatized zinc(II) phthalocyanines
topic_facet	Spectroscopy Synthesis Thiol-phthalocyanines (3 hydroxypropyl)ester 1,8 diazabicyclo[5.4.0]undec 7 ene 3 (3,4 dicyano phenoxy) propyl ester 4 nitrophthalonitrile alkene derivative butanol macrocyclic compound methoxide sodium nitrile phthalocyanine phthalocyanine zinc phthalonitrile sodium derivative sulfur thioacetic acid thiol derivative unclassified drug zinc acetate absorption spectrophotometry article chemical structure controlled study spectrofluorometry substitution reaction synthesis
description	Preparation and characterization of tetrasubstituted zinc(II) phthalocyanines in which sulfur is not linked to the macrocycle are reported herein for the first time. Thioacetic acid S-[3-(3,4-dicyano-phenoxy)-propyl]ester (4) was synthesized in 55% yield from 4-nitrophthalonitrile and thioacetic acid S-(3-hydroxy-propyl)ester (3). Tetrasusbtituted thiol-derivatized zinc(II) phthalocyanine 5 was obtained from 4 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene in butanol. Treatment of 5 with sodium methoxide afforded phthalocyanine 6. © 2009 Elsevier Ltd. All rights reserved.
author	Dicelio, Lelia Elina
author_facet	Dicelio, Lelia Elina
author_sort	Dicelio, Lelia Elina
title	Novel thiol-derivatized zinc(II) phthalocyanines
title_short	Novel thiol-derivatized zinc(II) phthalocyanines
title_full	Novel thiol-derivatized zinc(II) phthalocyanines
title_fullStr	Novel thiol-derivatized zinc(II) phthalocyanines
title_full_unstemmed	Novel thiol-derivatized zinc(II) phthalocyanines
title_sort	novel thiol-derivatized zinc(ii) phthalocyanines
publishDate	2009
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v50_n21_p2467_GarciaVior http://hdl.handle.net/20.500.12110/paper_00404039_v50_n21_p2467_GarciaVior
work_keys_str_mv	AT dicelioleliaelina novelthiolderivatizedzinciiphthalocyanines
_version_	1768543552166428672

Novel thiol-derivatized zinc(II) phthalocyanines

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