Unusual dealkylations and rearrangements in aromatic nucleophilic substitution
The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and...
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1980
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v21_n35_p3331_Nudelman http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman |
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paper:paper_00404039_v21_n35_p3331_Nudelman2023-06-08T15:04:20Z Unusual dealkylations and rearrangements in aromatic nucleophilic substitution Socolovsky, Susana Emilia The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine. A carbanionic mechanism is proposed. © 1980. Fil:Socolovsky, S.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1980 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v21_n35_p3331_Nudelman http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
The reaction of 2,4-dinitrohalobenzenes with di-isopropylamine produces mainly N-(2,4-dinitrophenyl)-isopropylamine and N-(2,4-dinitrophenyl)-n-propylamine instead of the expected straightforward substitution product. Dealkylations are also observed in the reactions with isopropylcyclohexylamine and dicyclohexylamine. A carbanionic mechanism is proposed. © 1980. |
author |
Socolovsky, Susana Emilia |
spellingShingle |
Socolovsky, Susana Emilia Unusual dealkylations and rearrangements in aromatic nucleophilic substitution |
author_facet |
Socolovsky, Susana Emilia |
author_sort |
Socolovsky, Susana Emilia |
title |
Unusual dealkylations and rearrangements in aromatic nucleophilic substitution |
title_short |
Unusual dealkylations and rearrangements in aromatic nucleophilic substitution |
title_full |
Unusual dealkylations and rearrangements in aromatic nucleophilic substitution |
title_fullStr |
Unusual dealkylations and rearrangements in aromatic nucleophilic substitution |
title_full_unstemmed |
Unusual dealkylations and rearrangements in aromatic nucleophilic substitution |
title_sort |
unusual dealkylations and rearrangements in aromatic nucleophilic substitution |
publishDate |
1980 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404039_v21_n35_p3331_Nudelman http://hdl.handle.net/20.500.12110/paper_00404039_v21_n35_p3331_Nudelman |
work_keys_str_mv |
AT socolovskysusanaemilia unusualdealkylationsandrearrangementsinaromaticnucleophilicsubstitution |
_version_ |
1768542403213393920 |