Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols

The UV irradiation of aromatic alcohols leads to the formation of several products: carbonyl compounds, ethers, α-glycols and tetra-aryl-1,4-dioxanes. The photoformation of α-glycols is qualitatively and quantitatively compared to the photoreduction of the carbonyl compounds. It is noteworthy that t...

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Autor principal: Frasca, Adolfo Rafael
Publicado: 1982
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v38_n16_p2525_Balsells
http://hdl.handle.net/20.500.12110/paper_00404020_v38_n16_p2525_Balsells
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00404020_v38_n16_p2525_Balsells
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spelling paper:paper_00404020_v38_n16_p2525_Balsells2023-06-08T15:04:08Z Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols Frasca, Adolfo Rafael The UV irradiation of aromatic alcohols leads to the formation of several products: carbonyl compounds, ethers, α-glycols and tetra-aryl-1,4-dioxanes. The photoformation of α-glycols is qualitatively and quantitatively compared to the photoreduction of the carbonyl compounds. It is noteworthy that the glycols are formed with a stereochemistry very different depending upon whether the substrate is an alcohol or a carbonyl compound. The structure, configuration and conformation of the 1-4-dixoanes obtained are studies as well as their origin. Other aspects of the photochemistry of the alcohols are analyzed using hydroperoxides as model substrates. © 1982. Fil:Frasca, A.R. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1982 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v38_n16_p2525_Balsells http://hdl.handle.net/20.500.12110/paper_00404020_v38_n16_p2525_Balsells
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description The UV irradiation of aromatic alcohols leads to the formation of several products: carbonyl compounds, ethers, α-glycols and tetra-aryl-1,4-dioxanes. The photoformation of α-glycols is qualitatively and quantitatively compared to the photoreduction of the carbonyl compounds. It is noteworthy that the glycols are formed with a stereochemistry very different depending upon whether the substrate is an alcohol or a carbonyl compound. The structure, configuration and conformation of the 1-4-dixoanes obtained are studies as well as their origin. Other aspects of the photochemistry of the alcohols are analyzed using hydroperoxides as model substrates. © 1982.
author Frasca, Adolfo Rafael
spellingShingle Frasca, Adolfo Rafael
Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
author_facet Frasca, Adolfo Rafael
author_sort Frasca, Adolfo Rafael
title Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_short Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_full Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_fullStr Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_full_unstemmed Photochemical reaction of alcohols-II. Irradiation of aromatic alcohols
title_sort photochemical reaction of alcohols-ii. irradiation of aromatic alcohols
publishDate 1982
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00404020_v38_n16_p2525_Balsells
http://hdl.handle.net/20.500.12110/paper_00404020_v38_n16_p2525_Balsells
work_keys_str_mv AT frascaadolforafael photochemicalreactionofalcoholsiiirradiationofaromaticalcohols
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