Reduction of an amido zinc(II) phthalocyanine by diborane
1,2-Dicyano-4,5-di[(N,N-dimethylaminocarbonyl)methoxy]benzene (5) was synthesized in 80% yield from the corresponding 1,2-dibromo derivative 4. Octa(peripheral-amide)substituted zinc(II) phthalocyanine 6 was obtained from 5 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Phth...
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2006
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00397881_v_n5_p799_Strassert http://hdl.handle.net/20.500.12110/paper_00397881_v_n5_p799_Strassert |
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paper:paper_00397881_v_n5_p799_Strassert2023-06-08T15:03:39Z Reduction of an amido zinc(II) phthalocyanine by diborane Dicelio, Lelia Elina Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Nucleophilic aromatic substitution Phthalocyanines Reduction Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction 1,2-Dicyano-4,5-di[(N,N-dimethylaminocarbonyl)methoxy]benzene (5) was synthesized in 80% yield from the corresponding 1,2-dibromo derivative 4. Octa(peripheral-amide)substituted zinc(II) phthalocyanine 6 was obtained from 5 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Phthalocyanine 7 was prepared via reduction of 6 with diborane. Treatment of 7 with methyl iodide afforded cationic dye 8. © Georg Thieme Verlag Stuttgart. Fil:Dicelio, L.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00397881_v_n5_p799_Strassert http://hdl.handle.net/20.500.12110/paper_00397881_v_n5_p799_Strassert |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Nucleophilic aromatic substitution Phthalocyanines Reduction Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction |
| spellingShingle |
Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Nucleophilic aromatic substitution Phthalocyanines Reduction Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction Dicelio, Lelia Elina Reduction of an amido zinc(II) phthalocyanine by diborane |
| topic_facet |
Nucleophilic aromatic substitution Phthalocyanines Reduction Dyes Positive ions Nucleophilic aromatic substitution Phthalocyanines Reduction Semiconducting zinc compounds 1,2 dicyano 4,5 di[(n,n dimethylaminocarbonyl)methoxy]benzene 1,8 diazabicyclo[5.4.0]undec 7 ene 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminocarbonyl)methoxy]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n dimethylaminoethoxy)]phthalocyaninatozinc(ii) 2,3,9,10,16,17,23,24 octakis[(n,n,n triethylammonium)ethoxy]phthalocyaninatozinc(ii)octaiodide amido zinc(ii) phthalocyanine benzene derivative heterocyclic compound phthalocyanine derivative unclassified drug zinc acetate article drug synthesis matrix assisted laser desorption ionization time of flight mass spectrometry proton nuclear magnetic resonance reduction substitution reaction |
| description |
1,2-Dicyano-4,5-di[(N,N-dimethylaminocarbonyl)methoxy]benzene (5) was synthesized in 80% yield from the corresponding 1,2-dibromo derivative 4. Octa(peripheral-amide)substituted zinc(II) phthalocyanine 6 was obtained from 5 and zinc acetate in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene. Phthalocyanine 7 was prepared via reduction of 6 with diborane. Treatment of 7 with methyl iodide afforded cationic dye 8. © Georg Thieme Verlag Stuttgart. |
| author |
Dicelio, Lelia Elina |
| author_facet |
Dicelio, Lelia Elina |
| author_sort |
Dicelio, Lelia Elina |
| title |
Reduction of an amido zinc(II) phthalocyanine by diborane |
| title_short |
Reduction of an amido zinc(II) phthalocyanine by diborane |
| title_full |
Reduction of an amido zinc(II) phthalocyanine by diborane |
| title_fullStr |
Reduction of an amido zinc(II) phthalocyanine by diborane |
| title_full_unstemmed |
Reduction of an amido zinc(II) phthalocyanine by diborane |
| title_sort |
reduction of an amido zinc(ii) phthalocyanine by diborane |
| publishDate |
2006 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00397881_v_n5_p799_Strassert http://hdl.handle.net/20.500.12110/paper_00397881_v_n5_p799_Strassert |
| work_keys_str_mv |
AT dicelioleliaelina reductionofanamidozinciiphthalocyaninebydiborane |
| _version_ |
1768546667437490176 |