Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3
The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternativ...
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1995
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v60_n7_p434_Gros http://hdl.handle.net/20.500.12110/paper_0039128X_v60_n7_p434_Gros |
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paper:paper_0039128X_v60_n7_p434_Gros2023-06-08T15:03:15Z Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 Gros, Eduardo Gervasio cleavage of epoxides ring A steroidal elimination steroidal epoxides epoxide lithium chloride n,n dimethylacetamide steroid article chemical reaction degradation ph proton nuclear magnetic resonance Cations Epoxy Compounds Lithium Molecular Structure Solvents Steroids Support, Non-U.S. Gov't The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternative mechanisms are presented. © 1995. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1995 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v60_n7_p434_Gros http://hdl.handle.net/20.500.12110/paper_0039128X_v60_n7_p434_Gros |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
cleavage of epoxides ring A steroidal elimination steroidal epoxides epoxide lithium chloride n,n dimethylacetamide steroid article chemical reaction degradation ph proton nuclear magnetic resonance Cations Epoxy Compounds Lithium Molecular Structure Solvents Steroids Support, Non-U.S. Gov't |
| spellingShingle |
cleavage of epoxides ring A steroidal elimination steroidal epoxides epoxide lithium chloride n,n dimethylacetamide steroid article chemical reaction degradation ph proton nuclear magnetic resonance Cations Epoxy Compounds Lithium Molecular Structure Solvents Steroids Support, Non-U.S. Gov't Gros, Eduardo Gervasio Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
| topic_facet |
cleavage of epoxides ring A steroidal elimination steroidal epoxides epoxide lithium chloride n,n dimethylacetamide steroid article chemical reaction degradation ph proton nuclear magnetic resonance Cations Epoxy Compounds Lithium Molecular Structure Solvents Steroids Support, Non-U.S. Gov't |
| description |
The particular behavior of 5β,6β steroidal epoxides carrying different groups at C-3 was studied. These epoxides may exhibit different cleavage behavior according to the nature of the solvent, the acid-base state of the medium, and the leaving abilities of the C-3 substituent. Results and alternative mechanisms are presented. © 1995. |
| author |
Gros, Eduardo Gervasio |
| author_facet |
Gros, Eduardo Gervasio |
| author_sort |
Gros, Eduardo Gervasio |
| title |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
| title_short |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
| title_full |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
| title_fullStr |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
| title_full_unstemmed |
Cleavage reaction of 5β,6β steroidal epoxides carrying different groups at C-3 |
| title_sort |
cleavage reaction of 5β,6β steroidal epoxides carrying different groups at c-3 |
| publishDate |
1995 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v60_n7_p434_Gros http://hdl.handle.net/20.500.12110/paper_0039128X_v60_n7_p434_Gros |
| work_keys_str_mv |
AT groseduardogervasio cleavagereactionof5b6bsteroidalepoxidescarryingdifferentgroupsatc3 |
| _version_ |
1768543125941256192 |