Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one

A short and efficient preparation of 17a-methyl-, 17a-ethyl-, 17a-allyl-, and 17a-benzyl-3β-acetoxy-17a-aza-d-homoandrost-5-en-17-one, as well as 17a-methyl-, 17a-ethyl-, and 17a-allyl-3β-methoxy-17a-aza-s-homoandrost-5-en-17-one from the corresponding androsten-17-one derivatives is described. (Ste...

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Autores principales: Revelli, Gustavo Ariel, Gros, Eduardo Gervasio
Publicado: 1993
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v58_n4_p181_Revelli
http://hdl.handle.net/20.500.12110/paper_0039128X_v58_n4_p181_Revelli
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spelling paper:paper_0039128X_v58_n4_p181_Revelli2023-06-08T15:03:14Z Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one Revelli, Gustavo Ariel Gros, Eduardo Gervasio 17a-aza-d-homoandrost-5-en-17-one derivatives 13C nuclear magnetic resonance spectra 1H nuclear magnetic resonance spectra azasteroids synthesis 17a allyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one 17a allyl 3beta methoxy 17a aza d homoandrost 5 en 17 one 17a benzyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one 17a ethyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one 17a ethyl 3beta methoxy 17a aza d homoandrost 5 en 17 one 17a methyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one 17a methyl 3beta methoxy 17a aza d homoandrost 5 en 17 one 3beta acetoxy 17a aza d homoandrost 5 en 17 one 3beta methoxy 17a aza d homoandrost 5 en 17 one azasteroid unclassified drug article carbon nuclear magnetic resonance drug structure drug synthesis mass spectrometry proton nuclear magnetic resonance Androstenols Azasteroids Magnetic Resonance Spectroscopy Molecular Structure Support, Non-U.S. Gov't A short and efficient preparation of 17a-methyl-, 17a-ethyl-, 17a-allyl-, and 17a-benzyl-3β-acetoxy-17a-aza-d-homoandrost-5-en-17-one, as well as 17a-methyl-, 17a-ethyl-, and 17a-allyl-3β-methoxy-17a-aza-s-homoandrost-5-en-17-one from the corresponding androsten-17-one derivatives is described. (Steroids 58:181-184, 1993). © 1993. Fil:Revelli, G.A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Gros, E.G. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1993 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v58_n4_p181_Revelli http://hdl.handle.net/20.500.12110/paper_0039128X_v58_n4_p181_Revelli
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic 17a-aza-d-homoandrost-5-en-17-one derivatives
13C nuclear magnetic resonance spectra
1H nuclear magnetic resonance spectra
azasteroids
synthesis
17a allyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a allyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
17a benzyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a ethyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a ethyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
17a methyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a methyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
3beta acetoxy 17a aza d homoandrost 5 en 17 one
3beta methoxy 17a aza d homoandrost 5 en 17 one
azasteroid
unclassified drug
article
carbon nuclear magnetic resonance
drug structure
drug synthesis
mass spectrometry
proton nuclear magnetic resonance
Androstenols
Azasteroids
Magnetic Resonance Spectroscopy
Molecular Structure
Support, Non-U.S. Gov't
spellingShingle 17a-aza-d-homoandrost-5-en-17-one derivatives
13C nuclear magnetic resonance spectra
1H nuclear magnetic resonance spectra
azasteroids
synthesis
17a allyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a allyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
17a benzyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a ethyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a ethyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
17a methyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a methyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
3beta acetoxy 17a aza d homoandrost 5 en 17 one
3beta methoxy 17a aza d homoandrost 5 en 17 one
azasteroid
unclassified drug
article
carbon nuclear magnetic resonance
drug structure
drug synthesis
mass spectrometry
proton nuclear magnetic resonance
Androstenols
Azasteroids
Magnetic Resonance Spectroscopy
Molecular Structure
Support, Non-U.S. Gov't
Revelli, Gustavo Ariel
Gros, Eduardo Gervasio
Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one
topic_facet 17a-aza-d-homoandrost-5-en-17-one derivatives
13C nuclear magnetic resonance spectra
1H nuclear magnetic resonance spectra
azasteroids
synthesis
17a allyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a allyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
17a benzyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a ethyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a ethyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
17a methyl 3beta acetoxy 17a aza d homoandrost 5 en 17 one
17a methyl 3beta methoxy 17a aza d homoandrost 5 en 17 one
3beta acetoxy 17a aza d homoandrost 5 en 17 one
3beta methoxy 17a aza d homoandrost 5 en 17 one
azasteroid
unclassified drug
article
carbon nuclear magnetic resonance
drug structure
drug synthesis
mass spectrometry
proton nuclear magnetic resonance
Androstenols
Azasteroids
Magnetic Resonance Spectroscopy
Molecular Structure
Support, Non-U.S. Gov't
description A short and efficient preparation of 17a-methyl-, 17a-ethyl-, 17a-allyl-, and 17a-benzyl-3β-acetoxy-17a-aza-d-homoandrost-5-en-17-one, as well as 17a-methyl-, 17a-ethyl-, and 17a-allyl-3β-methoxy-17a-aza-s-homoandrost-5-en-17-one from the corresponding androsten-17-one derivatives is described. (Steroids 58:181-184, 1993). © 1993.
author Revelli, Gustavo Ariel
Gros, Eduardo Gervasio
author_facet Revelli, Gustavo Ariel
Gros, Eduardo Gervasio
author_sort Revelli, Gustavo Ariel
title Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one
title_short Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one
title_full Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one
title_fullStr Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one
title_full_unstemmed Synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one
title_sort synthesis of 17a-alkyl- and 17a-aryl-3β-acetoxy- and 3β-methoxy-17a-aza-d-homoandrost-5-en-17-one
publishDate 1993
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0039128X_v58_n4_p181_Revelli
http://hdl.handle.net/20.500.12110/paper_0039128X_v58_n4_p181_Revelli
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