Correlation of reactivity with structural factors in a series of Fe(II) substituted cobalt ferrites
A series of powdered cobalt ferrites, CoxFe3-xO4 with 0.66≤x<1.00 containing different amounts of FeII, were synthesized by a mild procedure, and their Fe and Co site occupancies and structural characteristics were explored using X-ray anomalous scattering and the Rietveld refinement method....
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Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00224596_v179_n7_p2237_Sileo http://hdl.handle.net/20.500.12110/paper_00224596_v179_n7_p2237_Sileo |
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paper:paper_00224596_v179_n7_p2237_Sileo2023-06-08T14:50:54Z Correlation of reactivity with structural factors in a series of Fe(II) substituted cobalt ferrites Sileo, Elsa Ester Cobalt ferrites Electron hopping Kinetic dissolution Rietveld method X-ray anomalous scattering Dissolution Iron compounds Molecular structure Reaction kinetics Substitution reactions Synthesis (chemical) X ray scattering Cobalt ferrites Electron hopping Kinetic dissolution Rietveld method X-ray anomalous scattering Cobalt compounds A series of powdered cobalt ferrites, CoxFe3-xO4 with 0.66≤x<1.00 containing different amounts of FeII, were synthesized by a mild procedure, and their Fe and Co site occupancies and structural characteristics were explored using X-ray anomalous scattering and the Rietveld refinement method. The dissolution kinetics, measured in 0.1 M oxalic acid aqueous solution at 70 °C, indicate in all cases the operation of a contracting volume rate law. The specific rates increased with the FeII content following approximately a second-order polynomial expression. This result suggests that the transfer of FeIII controls the dissolution rate, and that the leaching of a first layer of ions CoII and FeII leaves exposed a surface enriched in slower dissolving octahedral FeIII ions. Within this model, inner vicinal lattice FeII accelerates the rate of FeIII transfer via internal electron hopping. A chain mechanism, involving successive electron transfers, fits the data very well. © 2006 Elsevier Inc. All rights reserved. Fil:Sileo, E.E. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2006 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00224596_v179_n7_p2237_Sileo http://hdl.handle.net/20.500.12110/paper_00224596_v179_n7_p2237_Sileo |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
Cobalt ferrites Electron hopping Kinetic dissolution Rietveld method X-ray anomalous scattering Dissolution Iron compounds Molecular structure Reaction kinetics Substitution reactions Synthesis (chemical) X ray scattering Cobalt ferrites Electron hopping Kinetic dissolution Rietveld method X-ray anomalous scattering Cobalt compounds |
spellingShingle |
Cobalt ferrites Electron hopping Kinetic dissolution Rietveld method X-ray anomalous scattering Dissolution Iron compounds Molecular structure Reaction kinetics Substitution reactions Synthesis (chemical) X ray scattering Cobalt ferrites Electron hopping Kinetic dissolution Rietveld method X-ray anomalous scattering Cobalt compounds Sileo, Elsa Ester Correlation of reactivity with structural factors in a series of Fe(II) substituted cobalt ferrites |
topic_facet |
Cobalt ferrites Electron hopping Kinetic dissolution Rietveld method X-ray anomalous scattering Dissolution Iron compounds Molecular structure Reaction kinetics Substitution reactions Synthesis (chemical) X ray scattering Cobalt ferrites Electron hopping Kinetic dissolution Rietveld method X-ray anomalous scattering Cobalt compounds |
description |
A series of powdered cobalt ferrites, CoxFe3-xO4 with 0.66≤x<1.00 containing different amounts of FeII, were synthesized by a mild procedure, and their Fe and Co site occupancies and structural characteristics were explored using X-ray anomalous scattering and the Rietveld refinement method. The dissolution kinetics, measured in 0.1 M oxalic acid aqueous solution at 70 °C, indicate in all cases the operation of a contracting volume rate law. The specific rates increased with the FeII content following approximately a second-order polynomial expression. This result suggests that the transfer of FeIII controls the dissolution rate, and that the leaching of a first layer of ions CoII and FeII leaves exposed a surface enriched in slower dissolving octahedral FeIII ions. Within this model, inner vicinal lattice FeII accelerates the rate of FeIII transfer via internal electron hopping. A chain mechanism, involving successive electron transfers, fits the data very well. © 2006 Elsevier Inc. All rights reserved. |
author |
Sileo, Elsa Ester |
author_facet |
Sileo, Elsa Ester |
author_sort |
Sileo, Elsa Ester |
title |
Correlation of reactivity with structural factors in a series of Fe(II) substituted cobalt ferrites |
title_short |
Correlation of reactivity with structural factors in a series of Fe(II) substituted cobalt ferrites |
title_full |
Correlation of reactivity with structural factors in a series of Fe(II) substituted cobalt ferrites |
title_fullStr |
Correlation of reactivity with structural factors in a series of Fe(II) substituted cobalt ferrites |
title_full_unstemmed |
Correlation of reactivity with structural factors in a series of Fe(II) substituted cobalt ferrites |
title_sort |
correlation of reactivity with structural factors in a series of fe(ii) substituted cobalt ferrites |
publishDate |
2006 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00224596_v179_n7_p2237_Sileo http://hdl.handle.net/20.500.12110/paper_00224596_v179_n7_p2237_Sileo |
work_keys_str_mv |
AT sileoelsaester correlationofreactivitywithstructuralfactorsinaseriesoffeiisubstitutedcobaltferrites |
_version_ |
1768544307908706304 |