The reaction of phenyllithium with carbon monoxide

Three main products are obtained from the reaction between phenyllithium and carbon monoxide, namely: benzophenone (I), benzoin (II) and α,α-diphenyl-acetophenone (III). Evidence is given for the existence of benzoyllithium as the first intermediate of the reaction and for the subsequent intermediat...

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Publicado: 1983
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022328X_v241_n2_p143_Nudelman
http://hdl.handle.net/20.500.12110/paper_0022328X_v241_n2_p143_Nudelman
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_0022328X_v241_n2_p143_Nudelman
record_format dspace
spelling paper:paper_0022328X_v241_n2_p143_Nudelman2023-06-08T14:49:39Z The reaction of phenyllithium with carbon monoxide Three main products are obtained from the reaction between phenyllithium and carbon monoxide, namely: benzophenone (I), benzoin (II) and α,α-diphenyl-acetophenone (III). Evidence is given for the existence of benzoyllithium as the first intermediate of the reaction and for the subsequent intermediates in the production of I, II and III. The basic sequences followed in the formation of those and of other minor products are outlined in the Scheme. Reaction conditions can be adjusted to obtain III in a high yield or to prevent further reaction of the first intermediate and obtain diarylalkylcarbinols, or substituted tetrahydrofurans. © 1983. 1983 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022328X_v241_n2_p143_Nudelman http://hdl.handle.net/20.500.12110/paper_0022328X_v241_n2_p143_Nudelman
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Three main products are obtained from the reaction between phenyllithium and carbon monoxide, namely: benzophenone (I), benzoin (II) and α,α-diphenyl-acetophenone (III). Evidence is given for the existence of benzoyllithium as the first intermediate of the reaction and for the subsequent intermediates in the production of I, II and III. The basic sequences followed in the formation of those and of other minor products are outlined in the Scheme. Reaction conditions can be adjusted to obtain III in a high yield or to prevent further reaction of the first intermediate and obtain diarylalkylcarbinols, or substituted tetrahydrofurans. © 1983.
title The reaction of phenyllithium with carbon monoxide
spellingShingle The reaction of phenyllithium with carbon monoxide
title_short The reaction of phenyllithium with carbon monoxide
title_full The reaction of phenyllithium with carbon monoxide
title_fullStr The reaction of phenyllithium with carbon monoxide
title_full_unstemmed The reaction of phenyllithium with carbon monoxide
title_sort reaction of phenyllithium with carbon monoxide
publishDate 1983
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022328X_v241_n2_p143_Nudelman
http://hdl.handle.net/20.500.12110/paper_0022328X_v241_n2_p143_Nudelman
_version_ 1768545726510399488

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