Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines

From the spin-spin coupling constants of pyridine and monosubstituted pyridines the effects of several substituents have been calculated- Assuming an additivity relationship when two of these substituents are present in the same molecule, the spin-spin coupling constants for 11 disubstituted pyridin...

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Publicado: 1973
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222860_v16_n3_p451_DeKowalewski
http://hdl.handle.net/20.500.12110/paper_00222860_v16_n3_p451_DeKowalewski
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spelling paper:paper_00222860_v16_n3_p451_DeKowalewski2023-06-08T14:48:52Z Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines From the spin-spin coupling constants of pyridine and monosubstituted pyridines the effects of several substituents have been calculated- Assuming an additivity relationship when two of these substituents are present in the same molecule, the spin-spin coupling constants for 11 disubstituted pyridines have been calculated. The NMR spectra of 13 disubstituted pyridines have been studied to obtain accurate values of their coupling constants. The experimental values of these constants are in very good agreement with those calculated using the additivity relationships. © 1973. 1973 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222860_v16_n3_p451_DeKowalewski http://hdl.handle.net/20.500.12110/paper_00222860_v16_n3_p451_DeKowalewski
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description From the spin-spin coupling constants of pyridine and monosubstituted pyridines the effects of several substituents have been calculated- Assuming an additivity relationship when two of these substituents are present in the same molecule, the spin-spin coupling constants for 11 disubstituted pyridines have been calculated. The NMR spectra of 13 disubstituted pyridines have been studied to obtain accurate values of their coupling constants. The experimental values of these constants are in very good agreement with those calculated using the additivity relationships. © 1973.
title Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines
spellingShingle Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines
title_short Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines
title_full Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines
title_fullStr Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines
title_full_unstemmed Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines
title_sort additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines
publishDate 1973
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222860_v16_n3_p451_DeKowalewski
http://hdl.handle.net/20.500.12110/paper_00222860_v16_n3_p451_DeKowalewski
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