Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines
From the spin-spin coupling constants of pyridine and monosubstituted pyridines the effects of several substituents have been calculated- Assuming an additivity relationship when two of these substituents are present in the same molecule, the spin-spin coupling constants for 11 disubstituted pyridin...
Guardado en:
Publicado: |
1973
|
---|---|
Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222860_v16_n3_p451_DeKowalewski http://hdl.handle.net/20.500.12110/paper_00222860_v16_n3_p451_DeKowalewski |
Aporte de: |
id |
paper:paper_00222860_v16_n3_p451_DeKowalewski |
---|---|
record_format |
dspace |
spelling |
paper:paper_00222860_v16_n3_p451_DeKowalewski2023-06-08T14:48:52Z Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines From the spin-spin coupling constants of pyridine and monosubstituted pyridines the effects of several substituents have been calculated- Assuming an additivity relationship when two of these substituents are present in the same molecule, the spin-spin coupling constants for 11 disubstituted pyridines have been calculated. The NMR spectra of 13 disubstituted pyridines have been studied to obtain accurate values of their coupling constants. The experimental values of these constants are in very good agreement with those calculated using the additivity relationships. © 1973. 1973 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222860_v16_n3_p451_DeKowalewski http://hdl.handle.net/20.500.12110/paper_00222860_v16_n3_p451_DeKowalewski |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
description |
From the spin-spin coupling constants of pyridine and monosubstituted pyridines the effects of several substituents have been calculated- Assuming an additivity relationship when two of these substituents are present in the same molecule, the spin-spin coupling constants for 11 disubstituted pyridines have been calculated. The NMR spectra of 13 disubstituted pyridines have been studied to obtain accurate values of their coupling constants. The experimental values of these constants are in very good agreement with those calculated using the additivity relationships. © 1973. |
title |
Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines |
spellingShingle |
Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines |
title_short |
Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines |
title_full |
Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines |
title_fullStr |
Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines |
title_full_unstemmed |
Additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines |
title_sort |
additivity of substituent effects on the proton-proton coupling constants of disubstituted pyridines |
publishDate |
1973 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00222860_v16_n3_p451_DeKowalewski http://hdl.handle.net/20.500.12110/paper_00222860_v16_n3_p451_DeKowalewski |
_version_ |
1768546146777563136 |