Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III
Synthesis of (3′R) 2-acetamido-4-N-acetyl-3′-spiro-[1′,2′:5′,6′- di-O-isopropylidene-α-D-glucofuranosyl]1,3,4-thiadiazoline diastereomerically pure is described. We report the physical and spectroscopic characterization of the new heterocyclic compound as well as its immediate precursors. We discuss...
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2002
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| Acceso en línea: | https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022152X_v39_n1_p137_MartinsAlho http://hdl.handle.net/20.500.12110/paper_0022152X_v39_n1_p137_MartinsAlho |
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paper:paper_0022152X_v39_n1_p137_MartinsAlho2023-06-08T14:46:48Z Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III 2 acetamido 4 n acetyl 3' spiro[1',2':5',6' di o isopropylidene alpha dextro glucofuranosyl] 1,3,4 thiadiazoline carbohydrate heterocyclic compound thiosemicarbazone derivative unclassified drug article carbon nuclear magnetic resonance chemical structure chirality cyclization diastereoisomer isomerism nuclear Overhauser effect proton nuclear magnetic resonance spectroscopy stereochemistry synthesis Synthesis of (3′R) 2-acetamido-4-N-acetyl-3′-spiro-[1′,2′:5′,6′- di-O-isopropylidene-α-D-glucofuranosyl]1,3,4-thiadiazoline diastereomerically pure is described. We report the physical and spectroscopic characterization of the new heterocyclic compound as well as its immediate precursors. We discuss also the possibilities for cyclization and established the stereochemistry of the new stereogenic center. 2002 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022152X_v39_n1_p137_MartinsAlho http://hdl.handle.net/20.500.12110/paper_0022152X_v39_n1_p137_MartinsAlho |
| institution |
Universidad de Buenos Aires |
| institution_str |
I-28 |
| repository_str |
R-134 |
| collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
| topic |
2 acetamido 4 n acetyl 3' spiro[1',2':5',6' di o isopropylidene alpha dextro glucofuranosyl] 1,3,4 thiadiazoline carbohydrate heterocyclic compound thiosemicarbazone derivative unclassified drug article carbon nuclear magnetic resonance chemical structure chirality cyclization diastereoisomer isomerism nuclear Overhauser effect proton nuclear magnetic resonance spectroscopy stereochemistry synthesis |
| spellingShingle |
2 acetamido 4 n acetyl 3' spiro[1',2':5',6' di o isopropylidene alpha dextro glucofuranosyl] 1,3,4 thiadiazoline carbohydrate heterocyclic compound thiosemicarbazone derivative unclassified drug article carbon nuclear magnetic resonance chemical structure chirality cyclization diastereoisomer isomerism nuclear Overhauser effect proton nuclear magnetic resonance spectroscopy stereochemistry synthesis Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III |
| topic_facet |
2 acetamido 4 n acetyl 3' spiro[1',2':5',6' di o isopropylidene alpha dextro glucofuranosyl] 1,3,4 thiadiazoline carbohydrate heterocyclic compound thiosemicarbazone derivative unclassified drug article carbon nuclear magnetic resonance chemical structure chirality cyclization diastereoisomer isomerism nuclear Overhauser effect proton nuclear magnetic resonance spectroscopy stereochemistry synthesis |
| description |
Synthesis of (3′R) 2-acetamido-4-N-acetyl-3′-spiro-[1′,2′:5′,6′- di-O-isopropylidene-α-D-glucofuranosyl]1,3,4-thiadiazoline diastereomerically pure is described. We report the physical and spectroscopic characterization of the new heterocyclic compound as well as its immediate precursors. We discuss also the possibilities for cyclization and established the stereochemistry of the new stereogenic center. |
| title |
Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III |
| title_short |
Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III |
| title_full |
Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III |
| title_fullStr |
Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III |
| title_full_unstemmed |
Synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - Part III |
| title_sort |
synthesis and characterization of some heterocyclic derivatives by cyclization of carbohydrate thiosemicarbazone - part iii |
| publishDate |
2002 |
| url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_0022152X_v39_n1_p137_MartinsAlho http://hdl.handle.net/20.500.12110/paper_0022152X_v39_n1_p137_MartinsAlho |
| _version_ |
1768544897299644416 |