The potential-dependence of the transfer coefficient in the cr(II)/cr(III) reaction

Current-voltage curves for the Cr(II)/Cr(III) electrode reaction at the d.m.e. in acidified 0.5 M NaClO4 have been measured and analysed by koutecky's method. After correction of the apparent rate constants for double-layer effects by the method proposed by Frumkin, the transfer coefficient sho...

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Publicado: 1966
Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220728_v12_n5-6_p524_Parsons
http://hdl.handle.net/20.500.12110/paper_00220728_v12_n5-6_p524_Parsons
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Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires
id paper:paper_00220728_v12_n5-6_p524_Parsons
record_format dspace
spelling paper:paper_00220728_v12_n5-6_p524_Parsons2023-06-08T14:45:18Z The potential-dependence of the transfer coefficient in the cr(II)/cr(III) reaction Current-voltage curves for the Cr(II)/Cr(III) electrode reaction at the d.m.e. in acidified 0.5 M NaClO4 have been measured and analysed by koutecky's method. After correction of the apparent rate constants for double-layer effects by the method proposed by Frumkin, the transfer coefficient shows a potential-dependence which is in quantitative agreement with current theories of electron-transfer reactions. © 1966. 1966 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220728_v12_n5-6_p524_Parsons http://hdl.handle.net/20.500.12110/paper_00220728_v12_n5-6_p524_Parsons
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
description Current-voltage curves for the Cr(II)/Cr(III) electrode reaction at the d.m.e. in acidified 0.5 M NaClO4 have been measured and analysed by koutecky's method. After correction of the apparent rate constants for double-layer effects by the method proposed by Frumkin, the transfer coefficient shows a potential-dependence which is in quantitative agreement with current theories of electron-transfer reactions. © 1966.
title The potential-dependence of the transfer coefficient in the cr(II)/cr(III) reaction
spellingShingle The potential-dependence of the transfer coefficient in the cr(II)/cr(III) reaction
title_short The potential-dependence of the transfer coefficient in the cr(II)/cr(III) reaction
title_full The potential-dependence of the transfer coefficient in the cr(II)/cr(III) reaction
title_fullStr The potential-dependence of the transfer coefficient in the cr(II)/cr(III) reaction
title_full_unstemmed The potential-dependence of the transfer coefficient in the cr(II)/cr(III) reaction
title_sort potential-dependence of the transfer coefficient in the cr(ii)/cr(iii) reaction
publishDate 1966
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220728_v12_n5-6_p524_Parsons
http://hdl.handle.net/20.500.12110/paper_00220728_v12_n5-6_p524_Parsons
_version_ 1768544581708677120

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