Growth kinetics of ISOVPE HgCdTe epilayers obtained on alloyed CdTe substrates with different crystalline orientations
Hg1-xCdxTe (MCT) epilayers were grown on (1 1 1)Cd, (1 1 1)Te, (1 1 0) and (1 0 0) CdZnTe and CdTeSe substrates by isothermal vapor phase epitaxy (ISOVPE). The growth kinetics of the epilayers were studied by a non-linear diffusive convective model for the ISOVPE MCT growth, which was assessed in a...
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paper:paper_00220248_v312_n9_p1481_Gilabert2023-06-08T14:45:05Z Growth kinetics of ISOVPE HgCdTe epilayers obtained on alloyed CdTe substrates with different crystalline orientations Gilabert, Ulises Eduardo Scarpettini, Alberto F. Trigubo, Alicia Beatriz A1. Growth models A3. Vapor phase epitaxy B1. Cadmium compounds B2. Semiconducting II-VI materials A1. Growth models A3. Vapor phase epitaxy CdTe Composition profile Crystalline orientations Discrete mathematics Epilayers grown Experimental conditions Finite rate Growth models Growth techniques HgCdTe Isothermal vapor phase epitaxy Mixed controls MOCVD Non-linear Nonlinear diffusion Numerical values Semiconducting II-VI materials Bioactivity Cadmium Cadmium alloys Cadmium compounds Chemical vapor deposition Crystal growth Crystalline materials Epilayers Growth kinetics Mathematical techniques Mercury (metal) Mercury compounds Rate constants Semiconductor growth Substrates Surface reactions Vapor phase epitaxy Vapors Film growth Hg1-xCdxTe (MCT) epilayers were grown on (1 1 1)Cd, (1 1 1)Te, (1 1 0) and (1 0 0) CdZnTe and CdTeSe substrates by isothermal vapor phase epitaxy (ISOVPE). The growth kinetics of the epilayers were studied by a non-linear diffusive convective model for the ISOVPE MCT growth, which was assessed in a previous paper . The non-linear diffusion-convection problem, which describes ISOVPE MCT film growth, was numerically solved by means of discrete mathematics. As the theoretical and experimental composition profiles were remarkably different in accordance with the epilayers grown over pure CdTe substrates, in the model a finite rate in the surface reaction rate constant that enabled a good fit was assumed. The numerical value of the surface reaction rate constant was similar for all the studied substrates and crystalline orientations, hence the results enabled us to determine that the deposition rate has a mixed control for the experimental conditions of this work. This isotropic characteristic of the ISOVPE technique for pure and alloyed CdTe substrates is remarkable, quite different from other MCT growth techniques as MBE or MOCVD. © 2010 Elsevier B.V. All rights reserved. Fil:Gilabert, U. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Scarpettini, A. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Trigubó, A.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2010 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220248_v312_n9_p1481_Gilabert http://hdl.handle.net/20.500.12110/paper_00220248_v312_n9_p1481_Gilabert |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
A1. Growth models A3. Vapor phase epitaxy B1. Cadmium compounds B2. Semiconducting II-VI materials A1. Growth models A3. Vapor phase epitaxy CdTe Composition profile Crystalline orientations Discrete mathematics Epilayers grown Experimental conditions Finite rate Growth models Growth techniques HgCdTe Isothermal vapor phase epitaxy Mixed controls MOCVD Non-linear Nonlinear diffusion Numerical values Semiconducting II-VI materials Bioactivity Cadmium Cadmium alloys Cadmium compounds Chemical vapor deposition Crystal growth Crystalline materials Epilayers Growth kinetics Mathematical techniques Mercury (metal) Mercury compounds Rate constants Semiconductor growth Substrates Surface reactions Vapor phase epitaxy Vapors Film growth |
spellingShingle |
A1. Growth models A3. Vapor phase epitaxy B1. Cadmium compounds B2. Semiconducting II-VI materials A1. Growth models A3. Vapor phase epitaxy CdTe Composition profile Crystalline orientations Discrete mathematics Epilayers grown Experimental conditions Finite rate Growth models Growth techniques HgCdTe Isothermal vapor phase epitaxy Mixed controls MOCVD Non-linear Nonlinear diffusion Numerical values Semiconducting II-VI materials Bioactivity Cadmium Cadmium alloys Cadmium compounds Chemical vapor deposition Crystal growth Crystalline materials Epilayers Growth kinetics Mathematical techniques Mercury (metal) Mercury compounds Rate constants Semiconductor growth Substrates Surface reactions Vapor phase epitaxy Vapors Film growth Gilabert, Ulises Eduardo Scarpettini, Alberto F. Trigubo, Alicia Beatriz Growth kinetics of ISOVPE HgCdTe epilayers obtained on alloyed CdTe substrates with different crystalline orientations |
topic_facet |
A1. Growth models A3. Vapor phase epitaxy B1. Cadmium compounds B2. Semiconducting II-VI materials A1. Growth models A3. Vapor phase epitaxy CdTe Composition profile Crystalline orientations Discrete mathematics Epilayers grown Experimental conditions Finite rate Growth models Growth techniques HgCdTe Isothermal vapor phase epitaxy Mixed controls MOCVD Non-linear Nonlinear diffusion Numerical values Semiconducting II-VI materials Bioactivity Cadmium Cadmium alloys Cadmium compounds Chemical vapor deposition Crystal growth Crystalline materials Epilayers Growth kinetics Mathematical techniques Mercury (metal) Mercury compounds Rate constants Semiconductor growth Substrates Surface reactions Vapor phase epitaxy Vapors Film growth |
description |
Hg1-xCdxTe (MCT) epilayers were grown on (1 1 1)Cd, (1 1 1)Te, (1 1 0) and (1 0 0) CdZnTe and CdTeSe substrates by isothermal vapor phase epitaxy (ISOVPE). The growth kinetics of the epilayers were studied by a non-linear diffusive convective model for the ISOVPE MCT growth, which was assessed in a previous paper . The non-linear diffusion-convection problem, which describes ISOVPE MCT film growth, was numerically solved by means of discrete mathematics. As the theoretical and experimental composition profiles were remarkably different in accordance with the epilayers grown over pure CdTe substrates, in the model a finite rate in the surface reaction rate constant that enabled a good fit was assumed. The numerical value of the surface reaction rate constant was similar for all the studied substrates and crystalline orientations, hence the results enabled us to determine that the deposition rate has a mixed control for the experimental conditions of this work. This isotropic characteristic of the ISOVPE technique for pure and alloyed CdTe substrates is remarkable, quite different from other MCT growth techniques as MBE or MOCVD. © 2010 Elsevier B.V. All rights reserved. |
author |
Gilabert, Ulises Eduardo Scarpettini, Alberto F. Trigubo, Alicia Beatriz |
author_facet |
Gilabert, Ulises Eduardo Scarpettini, Alberto F. Trigubo, Alicia Beatriz |
author_sort |
Gilabert, Ulises Eduardo |
title |
Growth kinetics of ISOVPE HgCdTe epilayers obtained on alloyed CdTe substrates with different crystalline orientations |
title_short |
Growth kinetics of ISOVPE HgCdTe epilayers obtained on alloyed CdTe substrates with different crystalline orientations |
title_full |
Growth kinetics of ISOVPE HgCdTe epilayers obtained on alloyed CdTe substrates with different crystalline orientations |
title_fullStr |
Growth kinetics of ISOVPE HgCdTe epilayers obtained on alloyed CdTe substrates with different crystalline orientations |
title_full_unstemmed |
Growth kinetics of ISOVPE HgCdTe epilayers obtained on alloyed CdTe substrates with different crystalline orientations |
title_sort |
growth kinetics of isovpe hgcdte epilayers obtained on alloyed cdte substrates with different crystalline orientations |
publishDate |
2010 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00220248_v312_n9_p1481_Gilabert http://hdl.handle.net/20.500.12110/paper_00220248_v312_n9_p1481_Gilabert |
work_keys_str_mv |
AT gilabertuliseseduardo growthkineticsofisovpehgcdteepilayersobtainedonalloyedcdtesubstrateswithdifferentcrystallineorientations AT scarpettinialbertof growthkineticsofisovpehgcdteepilayersobtainedonalloyedcdtesubstrateswithdifferentcrystallineorientations AT triguboaliciabeatriz growthkineticsofisovpehgcdteepilayersobtainedonalloyedcdtesubstrateswithdifferentcrystallineorientations |
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1768542491232960512 |