Volumetric properties of (4-methylphenol + NaOH) at high temperatures

The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methy...

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Autores principales: Mendez De Leo, Lucila Paula, Bianchi, Hugo Luis, Fernandez Prini, Roberto
Publicado: 2003
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Acceso en línea:https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219614_v35_n9_p1541_Kukuljan
http://hdl.handle.net/20.500.12110/paper_00219614_v35_n9_p1541_Kukuljan
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spelling paper:paper_00219614_v35_n9_p1541_Kukuljan2023-06-08T14:44:41Z Volumetric properties of (4-methylphenol + NaOH) at high temperatures Mendez De Leo, Lucila Paula Bianchi, Hugo Luis Fernandez Prini, Roberto 4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methylphenol (HCRES) and its sodium salt (NaCRES) were determined by the application of the Pitzer ion-interaction treatment to the solutions neglecting high order terms. The reported values of partial molar volume of 4-methylphenol are in good agreement with literature data. Fil:Méndez De Leo, L.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bianchi, H.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fernández-Prini, R.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2003 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219614_v35_n9_p1541_Kukuljan http://hdl.handle.net/20.500.12110/paper_00219614_v35_n9_p1541_Kukuljan
institution Universidad de Buenos Aires
institution_str I-28
repository_str R-134
collection Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic 4-Methylphenol
Densities
Equilibrium association constant
Partial molar volume
Sodium salt of 4-methylphenol
Density (specific gravity)
Phase equilibria
Phenols
Sodium compounds
Volume fraction
Equilibrium association constant
Partial molar volume
Thermodynamics
spellingShingle 4-Methylphenol
Densities
Equilibrium association constant
Partial molar volume
Sodium salt of 4-methylphenol
Density (specific gravity)
Phase equilibria
Phenols
Sodium compounds
Volume fraction
Equilibrium association constant
Partial molar volume
Thermodynamics
Mendez De Leo, Lucila Paula
Bianchi, Hugo Luis
Fernandez Prini, Roberto
Volumetric properties of (4-methylphenol + NaOH) at high temperatures
topic_facet 4-Methylphenol
Densities
Equilibrium association constant
Partial molar volume
Sodium salt of 4-methylphenol
Density (specific gravity)
Phase equilibria
Phenols
Sodium compounds
Volume fraction
Equilibrium association constant
Partial molar volume
Thermodynamics
description The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methylphenol (HCRES) and its sodium salt (NaCRES) were determined by the application of the Pitzer ion-interaction treatment to the solutions neglecting high order terms. The reported values of partial molar volume of 4-methylphenol are in good agreement with literature data.
author Mendez De Leo, Lucila Paula
Bianchi, Hugo Luis
Fernandez Prini, Roberto
author_facet Mendez De Leo, Lucila Paula
Bianchi, Hugo Luis
Fernandez Prini, Roberto
author_sort Mendez De Leo, Lucila Paula
title Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_short Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_full Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_fullStr Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_full_unstemmed Volumetric properties of (4-methylphenol + NaOH) at high temperatures
title_sort volumetric properties of (4-methylphenol + naoh) at high temperatures
publishDate 2003
url https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219614_v35_n9_p1541_Kukuljan
http://hdl.handle.net/20.500.12110/paper_00219614_v35_n9_p1541_Kukuljan
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AT bianchihugoluis volumetricpropertiesof4methylphenolnaohathightemperatures
AT fernandezpriniroberto volumetricpropertiesof4methylphenolnaohathightemperatures
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