Volumetric properties of (4-methylphenol + NaOH) at high temperatures
The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methy...
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2003
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paper:paper_00219614_v35_n9_p1541_Kukuljan2023-06-08T14:44:41Z Volumetric properties of (4-methylphenol + NaOH) at high temperatures Mendez De Leo, Lucila Paula Bianchi, Hugo Luis Fernandez Prini, Roberto 4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methylphenol (HCRES) and its sodium salt (NaCRES) were determined by the application of the Pitzer ion-interaction treatment to the solutions neglecting high order terms. The reported values of partial molar volume of 4-methylphenol are in good agreement with literature data. Fil:Méndez De Leo, L.P. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Bianchi, H.L. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Fernández-Prini, R.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 2003 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219614_v35_n9_p1541_Kukuljan http://hdl.handle.net/20.500.12110/paper_00219614_v35_n9_p1541_Kukuljan |
institution |
Universidad de Buenos Aires |
institution_str |
I-28 |
repository_str |
R-134 |
collection |
Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) |
topic |
4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics |
spellingShingle |
4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics Mendez De Leo, Lucila Paula Bianchi, Hugo Luis Fernandez Prini, Roberto Volumetric properties of (4-methylphenol + NaOH) at high temperatures |
topic_facet |
4-Methylphenol Densities Equilibrium association constant Partial molar volume Sodium salt of 4-methylphenol Density (specific gravity) Phase equilibria Phenols Sodium compounds Volume fraction Equilibrium association constant Partial molar volume Thermodynamics |
description |
The densities of aqueous solutions of 4-methylphenol and its mixtures with sodium hydroxide were measured as a function of concentration at T = 298 K at atmospheric pressure, and between the temperatures 373 K and 463 K at a pressure of 2 MPa. The partial molar volume at infinite dilution of 4-methylphenol (HCRES) and its sodium salt (NaCRES) were determined by the application of the Pitzer ion-interaction treatment to the solutions neglecting high order terms. The reported values of partial molar volume of 4-methylphenol are in good agreement with literature data. |
author |
Mendez De Leo, Lucila Paula Bianchi, Hugo Luis Fernandez Prini, Roberto |
author_facet |
Mendez De Leo, Lucila Paula Bianchi, Hugo Luis Fernandez Prini, Roberto |
author_sort |
Mendez De Leo, Lucila Paula |
title |
Volumetric properties of (4-methylphenol + NaOH) at high temperatures |
title_short |
Volumetric properties of (4-methylphenol + NaOH) at high temperatures |
title_full |
Volumetric properties of (4-methylphenol + NaOH) at high temperatures |
title_fullStr |
Volumetric properties of (4-methylphenol + NaOH) at high temperatures |
title_full_unstemmed |
Volumetric properties of (4-methylphenol + NaOH) at high temperatures |
title_sort |
volumetric properties of (4-methylphenol + naoh) at high temperatures |
publishDate |
2003 |
url |
https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00219614_v35_n9_p1541_Kukuljan http://hdl.handle.net/20.500.12110/paper_00219614_v35_n9_p1541_Kukuljan |
work_keys_str_mv |
AT mendezdeleolucilapaula volumetricpropertiesof4methylphenolnaohathightemperatures AT bianchihugoluis volumetricpropertiesof4methylphenolnaohathightemperatures AT fernandezpriniroberto volumetricpropertiesof4methylphenolnaohathightemperatures |
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1768546661573853184 |