Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model

The network structure of natural rubber (NR) achieved during vulcanization was analyzed using the model of rubber elasticity based on the tube concept, applied to the treatment of the stress-strain measurements. This theory allows the separation of constraint and crosslink contributions. Also, netwo...

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Detalles Bibliográficos
Autores principales:	Marzocca, Angel José, Cerveny, Silvina, Raimondo, Rosana Beatriz
Publicado:	1997
Materias:	Crosslink density NR vulcanizates Swelling Tube model Conformations Crosslinking Curing Density (specific gravity) Elasticity Mathematical models Molecular structure Strain measurement Vulcanization Conformation tube model Rubber
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca http://hdl.handle.net/20.500.12110/paper_00218995_v66_n6_p1085_Marzocca
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00218995_v66_n6_p1085_Marzocca
record_format	dspace
spelling	paper:paper_00218995_v66_n6_p1085_Marzocca2023-06-08T14:43:00Z Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model Marzocca, Angel José Cerveny, Silvina Raimondo, Rosana Beatriz Crosslink density NR vulcanizates Swelling Tube model Conformations Crosslinking Curing Density (specific gravity) Elasticity Mathematical models Molecular structure Strain measurement Swelling Vulcanization Conformation tube model Rubber The network structure of natural rubber (NR) achieved during vulcanization was analyzed using the model of rubber elasticity based on the tube concept, applied to the treatment of the stress-strain measurements. This theory allows the separation of constraint and crosslink contributions. Also, network parameters can be calculated. The crosslink level of the material was changed using different times and temperatures of cure. The change in the molecular parameters of the model with the degree of cure was estimated. The present research is useful for the precise determination of the chemical crosslink density of the NR network. The values were compared with those obtained by means of equilibrium volume swelling measurement. © 1997 John Wiley & Sons, Inc. Fil:Marzocca, A.J. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Cerveny, S. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Fil:Raimondo, R.B. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. 1997 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca http://hdl.handle.net/20.500.12110/paper_00218995_v66_n6_p1085_Marzocca
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	Crosslink density NR vulcanizates Swelling Tube model Conformations Crosslinking Curing Density (specific gravity) Elasticity Mathematical models Molecular structure Strain measurement Swelling Vulcanization Conformation tube model Rubber
spellingShingle	Crosslink density NR vulcanizates Swelling Tube model Conformations Crosslinking Curing Density (specific gravity) Elasticity Mathematical models Molecular structure Strain measurement Swelling Vulcanization Conformation tube model Rubber Marzocca, Angel José Cerveny, Silvina Raimondo, Rosana Beatriz Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model
topic_facet	Crosslink density NR vulcanizates Swelling Tube model Conformations Crosslinking Curing Density (specific gravity) Elasticity Mathematical models Molecular structure Strain measurement Swelling Vulcanization Conformation tube model Rubber
description	The network structure of natural rubber (NR) achieved during vulcanization was analyzed using the model of rubber elasticity based on the tube concept, applied to the treatment of the stress-strain measurements. This theory allows the separation of constraint and crosslink contributions. Also, network parameters can be calculated. The crosslink level of the material was changed using different times and temperatures of cure. The change in the molecular parameters of the model with the degree of cure was estimated. The present research is useful for the precise determination of the chemical crosslink density of the NR network. The values were compared with those obtained by means of equilibrium volume swelling measurement. © 1997 John Wiley & Sons, Inc.
author	Marzocca, Angel José Cerveny, Silvina Raimondo, Rosana Beatriz
author_facet	Marzocca, Angel José Cerveny, Silvina Raimondo, Rosana Beatriz
author_sort	Marzocca, Angel José
title	Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model
title_short	Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model
title_full	Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model
title_fullStr	Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model
title_full_unstemmed	Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model
title_sort	analysis of the variation of molecular parameters of nr during vulcanization in the frame of the conformational tube model
publishDate	1997
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v66_n6_p1085_Marzocca http://hdl.handle.net/20.500.12110/paper_00218995_v66_n6_p1085_Marzocca
work_keys_str_mv	AT marzoccaangeljose analysisofthevariationofmolecularparametersofnrduringvulcanizationintheframeoftheconformationaltubemodel AT cervenysilvina analysisofthevariationofmolecularparametersofnrduringvulcanizationintheframeoftheconformationaltubemodel AT raimondorosanabeatriz analysisofthevariationofmolecularparametersofnrduringvulcanizationintheframeoftheconformationaltubemodel
_version_	1768546052448714752

Analysis of the variation of molecular parameters of NR during vulcanization in the frame of the conformational tube model

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