Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers

Three new bisglycidyl monomers; 1,4-bis((2-hydroxy-3-methacryloxypropoxy) methyl)benzene (MB-Phe-OH), 1,4-bis(2-hydroxy-3-methacryloxypropoxy)2-cis-butene (MB-Cis-OH), and 1,7-bis(2-hydroxy-3-methacryloxypropoxy)heptane (MB-1,7-OH); were synthesized and used as Bis-GMA/TEGDMA (bisphenolglycidyl meth...

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Publicado:	2014
Materias:	biomaterials composites crosslinking photopolymerization resins Bending strength Biological materials Biomaterials Composite materials Crosslinking Dental composites Dental materials Mechanical properties Monomers Photopolymerization Composite resins Dental composite resins Dimethacrylates Double-bond conversions Flexural modulus Flexural properties Inorganic fillers Methacrylate monomers Resins
Acceso en línea:	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v131_n21_p_HerreraGonzalez http://hdl.handle.net/20.500.12110/paper_00218995_v131_n21_p_HerreraGonzalez
Aporte de:	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA) de Universidad de Buenos Aires

id	paper:paper_00218995_v131_n21_p_HerreraGonzalez
record_format	dspace
spelling	paper:paper_00218995_v131_n21_p_HerreraGonzalez2023-06-08T14:42:58Z Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers biomaterials composites crosslinking photopolymerization resins Bending strength Biological materials Biomaterials Composite materials Crosslinking Dental composites Dental materials Mechanical properties Monomers Photopolymerization Composite resins Dental composite resins Dimethacrylates Double-bond conversions Flexural modulus Flexural properties Inorganic fillers Methacrylate monomers Resins Three new bisglycidyl monomers; 1,4-bis((2-hydroxy-3-methacryloxypropoxy) methyl)benzene (MB-Phe-OH), 1,4-bis(2-hydroxy-3-methacryloxypropoxy)2-cis-butene (MB-Cis-OH), and 1,7-bis(2-hydroxy-3-methacryloxypropoxy)heptane (MB-1,7-OH); were synthesized and used as Bis-GMA/TEGDMA (bisphenolglycidyl methacrylate/triethylene glycol dimethacrylate) composite resin additives. Flexural properties and double bond conversion of the dental resins composed of silanizated inorganic filler and organic matrices containing new monomers were evaluated. The composite resins formulated, using the monomers MB-Cis-OH and MB-1,7-OH, have mechanical properties and double bond conversion comparable with those of Bis-GMA/TEGDMA composite resin used as control. The composite containing the new monomer MB-Phe-OH has better flexural properties (flexural strength 65.01 MPa and flexural modulus 5675.91 MPa) than the control composite resin (flexural strength 52.85 MPa and flexural modulus 4879.72 MPa); this could be attributed to the molecular structure of the monomer and its high double bond conversion level of 74.19%. The new bisglycidyl methacrylate monomer MB-Phe-OH could be potentially useful in the development of new organic matrices for dental composite resins with high double bond conversion and enhanced mechanical properties. © 2014 Wiley Periodicals, Inc. 2014 https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v131_n21_p_HerreraGonzalez http://hdl.handle.net/20.500.12110/paper_00218995_v131_n21_p_HerreraGonzalez
institution	Universidad de Buenos Aires
institution_str	I-28
repository_str	R-134
collection	Biblioteca Digital - Facultad de Ciencias Exactas y Naturales (UBA)
topic	biomaterials composites crosslinking photopolymerization resins Bending strength Biological materials Biomaterials Composite materials Crosslinking Dental composites Dental materials Mechanical properties Monomers Photopolymerization Composite resins Dental composite resins Dimethacrylates Double-bond conversions Flexural modulus Flexural properties Inorganic fillers Methacrylate monomers Resins
spellingShingle	biomaterials composites crosslinking photopolymerization resins Bending strength Biological materials Biomaterials Composite materials Crosslinking Dental composites Dental materials Mechanical properties Monomers Photopolymerization Composite resins Dental composite resins Dimethacrylates Double-bond conversions Flexural modulus Flexural properties Inorganic fillers Methacrylate monomers Resins Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
topic_facet	biomaterials composites crosslinking photopolymerization resins Bending strength Biological materials Biomaterials Composite materials Crosslinking Dental composites Dental materials Mechanical properties Monomers Photopolymerization Composite resins Dental composite resins Dimethacrylates Double-bond conversions Flexural modulus Flexural properties Inorganic fillers Methacrylate monomers Resins
description	Three new bisglycidyl monomers; 1,4-bis((2-hydroxy-3-methacryloxypropoxy) methyl)benzene (MB-Phe-OH), 1,4-bis(2-hydroxy-3-methacryloxypropoxy)2-cis-butene (MB-Cis-OH), and 1,7-bis(2-hydroxy-3-methacryloxypropoxy)heptane (MB-1,7-OH); were synthesized and used as Bis-GMA/TEGDMA (bisphenolglycidyl methacrylate/triethylene glycol dimethacrylate) composite resin additives. Flexural properties and double bond conversion of the dental resins composed of silanizated inorganic filler and organic matrices containing new monomers were evaluated. The composite resins formulated, using the monomers MB-Cis-OH and MB-1,7-OH, have mechanical properties and double bond conversion comparable with those of Bis-GMA/TEGDMA composite resin used as control. The composite containing the new monomer MB-Phe-OH has better flexural properties (flexural strength 65.01 MPa and flexural modulus 5675.91 MPa) than the control composite resin (flexural strength 52.85 MPa and flexural modulus 4879.72 MPa); this could be attributed to the molecular structure of the monomer and its high double bond conversion level of 74.19%. The new bisglycidyl methacrylate monomer MB-Phe-OH could be potentially useful in the development of new organic matrices for dental composite resins with high double bond conversion and enhanced mechanical properties. © 2014 Wiley Periodicals, Inc.
title	Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_short	Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_full	Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_fullStr	Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_full_unstemmed	Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
title_sort	composite resins based on novel and highly reactive bisglycidyl methacrylate monomers
publishDate	2014
url	https://bibliotecadigital.exactas.uba.ar/collection/paper/document/paper_00218995_v131_n21_p_HerreraGonzalez http://hdl.handle.net/20.500.12110/paper_00218995_v131_n21_p_HerreraGonzalez
_version_	1768544762804043776

Composite resins based on novel and highly reactive bisglycidyl methacrylate monomers

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